The refrigeration process reduces the temperature of a space or a given volume while the power generation process employs a source of thermal energy to generate electrical power. Because of the importance of these two processes, training of engineers in this area is of great interest. In engineering courses it is normally studied the vapor…

Obesity is the costliest preventable health problem in the United States. Understanding and applying the first law of thermodynamics will help students prevent and treat this all-too-common problem.

This paper describes a set of demonstration school experiments where infrared radiation is detected using thermal sensitive foils. The possibility of using standard glass lenses for infrared imaging is discussed in detail. It is shown that with optic components made from glass, infrared radiation up to 2.5 µm of wavelength can be detected. The…

Several educators have advocated teaching thermodynamics using a"global" approach in place of the conventional "local" approach. This article uses four examples of experiments to illustrate the two formulations and the definitions of heat and work associated with them. Advantages and disadvantages of both approaches are…

Variable temperature NMR spectroscopy is used to determine the ?H° and ?S° of hydrogen bond formation in a simple diamide. In this two- or three-day experiment, students synthesize N,N'-dimethylmalonamide, dimethylsuccinamide, dimethylglutaramide, or dimethyladipamide from methylamine and the corresponding diester (typically in 50% recrystallized…

In this laboratory activity, the equilibrium between square pyramidal and octahedral V(IV)O[superscript 2+] complexes is described. We propose a set of experiments to synthesize and characterize two types of V(IV)O[superscript 2+] complexes. The experiment allows great flexibility and may be effectively used at a variety of levels and the activity…

Thermodynamics, and in particular entropy, has been found to be challenging for students, not least due to its abstract character. Comparisons with more familiar and concrete domains, by means of analogy and metaphor, are commonly used in thermodynamics teaching, in particular the metaphor "entropy is disorder." However, this particular…

This study describes a research focused on grammar school students' misconceptions in the context of common, everyday thermal phenomena. Almost 500 Czech grammar school students from 24 classes were asked to fill in the reduced version of the Thermal Concept Evaluation in order to measure the asset of traditional instruction in eliminating…

Use of self-generated analogies has been proposed as a method for students to learn about a new subject by reference to what they previously know, in line with a constructivist perspective on learning and a resource perspective on conceptual change. We report on a group exercise on using completion problems in combination with self-generated…

We describe an activity-based approach for teaching aqueous solubility to introductory chemistry students that provides a more balanced presentation of the roles of energy and entropy in dissolution than is found in most general chemistry textbooks. In the first few activities, students observe that polar substances dissolve in water, whereas…

The recent introduction of inexpensive high-speed cameras offers a new experimental approach to many simple but fast-occurring events in physics. In this paper, the authors present two simple demonstration experiments recorded with high-speed cameras in the fields of gas dynamics and thermal physics. The experiments feature vapour pressure effects…

In the late 18th and throughout the 19th century, lead shot for muskets was prepared by use of a shot tower. Molten lead was poured from the top of a tower and, during its fall, the drops became spherical under the action of surface tension. In this article, we ask and answer the question: "How does the size of the lead shot depend on the height…

Stirling's approximation to ln "n"! is typically introduced to physical chemistry students as a step in the derivation of the statistical expression for the entropy. However, naive application of this approximation leads to incorrect conclusions. In this article, the problem is first illustrated using a familiar "toy…

Two computer-assisted experiments are described: (i) determination of the speed of ultrasound waves in water and (ii) measurement of the thermal expansion of an aluminum-based alloy. A new data-acquisition system developed by PASCO scientific is used. In both experiments, the "Keep" mode of recording data is employed: the data are…

The glass electrode is the most commonly used device to access the pH of an aqueous solution. It attains highly accurate measurements via simple and well-established procedures. However, the reasons why the glass electrode potential scales with hydrogen ion concentration according to almost Nernstian potential values have been long-standing…