The Achievement Goal Theory has been commonly used in the literature and the relation between the goal orientation construct and aspects of athletes' personality and well-being is an important element to be considered in the sports field. The objectives of this study were: (i) to confirm the reliability, factorial invariance and existence of latent mean differences of the Goal Orientations in Exercise Scale (GOES) in an Ecuadorian sample across sex; (ii) to identify the existence of subgroups of Ecuadorian students with different profiles of goal orientations to exercise; and (iii) to determine the differences in resilience and life satisfaction among these profiles. A total of 597 Ecuadorian students from the Sports Sciences degree participated in this study. Confirmatory factorial analysis supported the two-dimensional (ego-task) GOES structure. The GOES has an adequate reliability and structural invariance across sex. Significant latent mean differences on the "ego" orientation subscale were found across sex but not in the "task" one. Cluster analysis identified three task-ego orientation profiles: (1) moderately high on "task" and low on "ego"; (2) low on "task" and slightly high on "ego"; (3) high in both "task" and "ego" orientation. Post hoc comparisons showed statistical differences in resilience between the three profiles and in life satisfaction between the profile 3 and profiles 1 and 2. The current study allows the possibility of using the GOES as an invariant and reliable scale in Ecuadorian sample and initiates the use of goal orientation profiles and their relationship with resilience and life satisfaction in the sports field.