This manuscript aimed to develop an instrument assessing vocational values among students (VVS-S). The scale was developed in French using three different samples of Togolese participants for item development (N = 140), exploratory (N = 308) and confirmatory analyses (N = 300). It consists of 17 items divided into the five subscales of Power, Family, Helping, Salary, and Creativity. The correlational, higher-order, and bifactor models showed that these values could be considered independently. Moreover, four of the values correlated positively but weakly with life satisfaction. The VVS-S's usefulness for research and practice in counseling, particularly in sub-Saharan Africa, is discussed.