ERIC Number: EJ1269332
Record Type: Journal
Publication Date: 2020-Aug
Pages: 5
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: N/A
Available Date: N/A
Green Hydrogenation: Solvent-Free Hydrogenation of Pinenes for an Undergraduate Organic Chemistry Laboratory
Touaibia, Mohamed; Selka, Ayyoub; Levesque, Natalie A.; St-Onge, Pierre A.
Journal of Chemical Education, v97 n8 p2296-2301 Aug 2020
Reorienting organic chemistry laboratories with an emphasis on systemic thinking can only be beneficial to students. Addressing the challenges of climate change and the development of renewable resources with a fundamental reaction, such as the hydrogenation of an alkene, will allow students to see organic chemistry as a science beneficial to society. For this purpose, a green organic laboratory experiment in which students performed solvent-free catalytic hydrogenation of [beta]- or [alpha]-pinene was developed. Using a homemade high- or low-pressure autoclave, solvent-free hydrogenation of [beta]- or [alpha]-pinene over Pd/C produced a mixture of "cis"- and "trans"-pinanes. The monitoring of the reaction by NMR, IR, and GC-MS allowed the students to be familiar with the isomerization of an alkene and the shift of an equilibrium according to Le Chatelier's principle. The filtration of the catalyst near the halftime of reaction and the continuation of the hydrogenation off catalyst allowed the students to confirm the heterogeneous nature of the hydrogenation.
Descriptors: Organic Chemistry, Science Instruction, College Science, Undergraduate Study, Science Laboratories, Scientific Concepts, Concept Formation, Laboratory Experiments, Science Experiments
Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Descriptive
Education Level: Higher Education; Postsecondary Education
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A
Author Affiliations: N/A