This study conducts an intersectional analysis of two adjoined qualitative studies, reanalyzing the data using a college opportunity framework (González, Stoner, & Jovel, 2003) to examine how sources of social capital available within three high-"minority," high-poverty high schools in Texas shape college opportunities for Latina/o and Black high school students. Findings indicate that counselors and teachers were sources of college information and support while advanced courses prepared students for college-level curriculum. However, these same support mechanisms often deterred students' access to quality academic preparation and college information. The increased focus on state-mandated accountability measures at the schools also limited students' level of academic preparation and college access. Additionally, state college access policies designed to increase the college participation of underrepresented groups effectively accomplished this policy intent, but these same policies influenced students' college choice decisions.