This paper examines the relationship between specific documentaries and white student teachers' emotional responses to their viewing as part of a postgraduate teacher education course on educational equality. Documentaries are considered in terms of features (including elements of text), form (including stylistic conventions) and function in order to evaluate those elements most important in involving students emotionally. It argues that certain documentaries have the pedagogic "potential" to transform student thinking via the evocation of particular emotions which act to disturb white hegemonic practices, attitudes and cognitions. However, given that emotion is understood as integral to the operationalisation of whiteness, students' emotional responses are analysed from a critical whiteness perspective to reveal emotion as also potentially obstructive to student transformation. Hence, the paper shares the pedagogic decisions taken to capitalise on those emotional responses conducive to transformed student understandings and to stymie those which act as investment in whiteness to impede student development. Finally, it is argued that a conceptual lens is vital for understanding the relationship between documentaries and emotional responses in order that transformed thinking is enabled.