Strict partial order is a mathematical structure commonly seen in relational data. One obstacle to extracting such type of relations at scale is the lack of large scale labels for building effective data-driven solutions. We develop an active learning framework for mining such relations subject to a strict order. Our approach incorporates relational reasoning not only in finding new unlabeled pairs whose labels can be deduced from an existing label set, but also in devising new query strategies that consider the relational structure of labels. Our experiments on concept prerequisite relations show our proposed framework can substantially improve the classification performance with the same query budget compared to other baseline approaches. [For the full proceedings, see ED599096.]