Describes a procedure for the qualitative analysis of aluminum subgroup cations designed to avoid failure to obtain lead or barium chromate precipitates or failure to report aluminum hydroxide when present (due to staining). Provides a flow chart and step-by-step explanation for the new procedure, indicating significantly improved student results.…

Background information (including optical properties of inorganic materials) and procedures are provided for an experiment which introduces students to preparation of a doped semiconductor; phosphorescence; gettering procedures; reducing atmospheres; and use of a high-temperature furnace with associated thermocouples, temperature controllers, and…

This chemistry textbook presents a beginning course for schools or colleges. It presents a more complete classification than usual according to chemical analogies, the explanation of chemical phenomena in ordinary language, as well as symbols, and the addition of a complete set of formulae in the appendix. A number of recent and important…

This chemistry textbook presents a beginning course for schools or colleges. It presents a more complete classification than usual according to chemical analogies, the explanation of chemical phenomena in ordinary language, as well as symbols, and the addition of a complete set of formulae in the appendix. A number of recent and important…

Describes an 8-week project involving the synthesis of cobalt compounds. Once synthesized, compounds are qualitatively and quantitatively analyzed. Background information, laboratory procedures, and results/discussion are provided for three project experiments. (Author/JN)

Potential-pH diagrams show the domains of redoxpotential and pH in which major species are most stable. Constructing such diagrams provides students with opportunities to decide what species must be considered, search literature for equilibrium constants and free energies of formation, and practice in using the Nernst equation. (Author/JN)

Presents a list of resources on inorganic chemistry that includes general surveys, nomenclature, dictionaries, handbooks, compilations, and treatises. Selected for use by academic and student chemists. (DDR)

Described is an experiment in which factor analysis is used to identify and quantify the components of mixtures containing up to four species. Discussed are the theory, procedures, and sample results for this activity. (CW)

Incorporates the combined effects of ionic strength and ion association to show how calculations involving ionic equilibria are carried out. Examines the variability of reduction potential data for two aqueous redox systems. Provides several examples. (MVL)

Emphasizes the role that crystallography plays and has played in building up the body of chemical fact. Shows how the teaching of much of this material is illuminated by reference to crystal structures and crystallochemical relationships in all areas of chemistry. Discusses close packing, silicate structures, and salt hydrates. (CW)

Discusses a revised and extended version of the Mulliken electronegativities. Describes applications and limitations implied by this version. (CW)

Discusses the effects of using carbon dioxide contaminated sodium hydroxide solution as a titrant for a solution of a weak monoprotic acid and the resulting distortion of the titration curve in comparison to one obtained when an uncontaminated titrant is used. (CW)

Discusses a revision and extension of the Mulliken electronegativity scale to consider 50 elements. Describes the calculation of valence-state promotion energies and Mulliken atomic electronegativities and the conversion of Mulliken electronegativities to Pauling units. (CW)

Presents a quantitative treatment of ionization potentials of isoelectronic atoms. By looking at the single-electron view of calculating the total energy of an atom, trends in the screening and effective quantum number parameters are examined. Approaches the question of determining electron affinities. (CW)

Chemistry students selected a main group of the periodic table, researched the group, and then presented a 70-minute lecture on the group; conducted two lecture demonstrations; and performed two laboratory experiments. This was done to determine what descriptive chemistry should be included in a new sophomore-level inorganic chemistry course. (JN)