Applying the idea of green chemistry, we extended an esterification teaching experiment with isoamyl alcohol and acetic acid and reused isoamyl acetate in the transesterification reaction with KOH as the catalyst. As a result, isoamyl alcohol was produced and could be reused for the teaching experiment. The simplified experimental method achieved…

Benzoin, an [alpha]-hydroxy ketone, is stereoselectively reduced by sodium borohydride to yield hydrobenzoin, the stereochemistry of which is determined by acetalization and analysis of the derivative by NMR spectroscopy. This classical experiment has been enhanced by modern spectroscopic and computational analysis to enable students to…

A new experiment for use in introductory nanotechnology courses is described. This experiment allows students to fabricate metallic wires with microscale lateral dimensions and nanoscale vertical dimensions. Fabrication occurs in the capillaries of polydimethylsiloxane (PDMS) stamps modified with hydrophilic polymers. This experiment provides…

A set of inexpensive and pedagogically rich experiments focusing on S[subscript N]1, E1, and E2 reactions have been updated to include modern computational and spectroscopic analyses. The S[subscript N]1 experiment involves treatment of "tert"-amyl alcohol with hydrochloric acid to generate the corresponding alkyl chloride, which is used…

A laboratory experiment that involves the synthesis, characterization, and application exploration of a metal-organic framework (MOF) has been developed for first-year undergraduates in the Faculty of Engineering at National University of Singapore. The desired MOF material was prepared from commercially available reagents in a facile…

Biodiesel is an important biomass, largely employed in the transport sector and produced from vegetable oils. Additionally, waste cooking oils may be reused to produce biodiesel fuel, minimizing environmental pollution. A laboratory experiment that affords a widespread way to discuss degradation concepts and tools for used vegetable oil…

When injecting dye into a vortex, one finds that the dye remains captured around the vortex core over minutes, despite the fact that the vortex (and the dyed region) is strongly time-dependent. According to a recent theory, three-dimensional time-dependent vortices should be defined as rotating, material-holding regions of the fluid. Vortices…

Carbohydrates are an essential group of molecules to the organic chemistry classroom providing molecular relevance to a common ingredient in chemical biology. While the meticulous elucidation of the carbohydrate structures by Fischer and others is an engaging topic in the lecture, there are few laboratory experiments that can emulate carbohydrate…

A continuous flow photopinacol coupling of benzophenone has been developed and implemented in the undergraduate laboratory. This photoreduction was accomplished using 2-propanol as an H atom donor and cosolvent in the reaction. The simple and inexpensive UV light source and flow reactor design (less than $350/photochemical flow system) provide an…

Williamson ether experiments are commonly performed by students in undergraduate organic chemistry instructional laboratory courses. In this multioutcome experiment, students were provided 4-bromophenol and one of three alkyl halides: 1-bromopentane, 1-bromobutane, or 1-bromo-3-methylbutane. The alkyl halides served as the unknown component of the…

An undergraduate organic chemistry experiment has been developed that features asymmetric synthesis of an enantioenriched secondary alcohol, followed by determination of its absolute configuration using the competing enantioselective conversion (CEC) method. Students are given a ketone and an unknown enantiomer of CBS (Corey-Bakshi-Shibata)…

Virtual laboratories have started to be the leading alternative teaching tools during the COVID-19 pandemic process. The "Acid-Base" subject is among those that form the foundations of biochemistry. Students can learn the "Acid-Base" subject in a secure environment, with remote access through the use of virtual laboratory…

Our study evaluates students' approaches to and perceptions of the use of hands-on at-home laboratory kits (HALK) experiments, open-source computer-based simulations (OSCBS), and their combination (OSCBS-HALK) in undergraduate introductory asynchronous online physics courses. Anonymous survey data from students who had completed online physics…

In this communication, we describe five at-home laboratory experiments and demonstrations that complement a semester-long analytical chemistry curriculum. The experiments were successfully carried out by remote undergraduate students enrolled in a hybrid analytical chemistry course during the COVID-19 pandemic. Students used their personal…

Mobile phones are a widely used platform for educational apps, mobile health, and a variety of chemical tests. Here, we are working on a mobile phone-based physics lab (mPhysics) that uses a mobile phone's capabilities to run simple physics experiments and demonstrations. While a mobile phone can be used to analyze magnetic and optical properties…