After completing their introductory studies on thermodynamics at the university level, typically in a second-year university course, most students show a number of misconceptions. In this work, we identify some of those erroneous ideas and try to explain their origins. We also give a suggestion to attack the problem through a systematic and…

Energy and entropy are centerpieces of physics. Energy is typically introduced in the study of classical mechanics. Although energy in this context can be challenging, its use in thermodynamics and its connection with entropy seem to take on a special air of mystery. In this five-part series, I pinpoint ways around key areas of difficulty to…

Thermal physics is in the realm of everyday experience, underlies current environmental concerns, and underpins studies in sciences, health and engineering. In the state of NSW in Australia, the coverage of thermal topics in high school is minimal, and, hence, so is the conceptual understanding of students. This study takes a new approach at…

There is widespread agreement that science learning always builds upon students' existing ideas and that science teachers should possess knowledge of learners. This study aims at investigating pre-service science teachers' knowledge of student misconceptions and difficulties, a crucial component of PCK, on Newton's Third Law. A questionnaire was…

The aim of this study was to apply current pedagogical research in order to develop an effective course and exercise structure for a physical chemistry thermodynamics course intended for second or third year university students of chemistry. A mixed-method approach was used to measure the impact the changes had on student learning. In its final…

Bose-Einstein condensation (BEC) is discussed at the level of an advanced course of statistical thermodynamics, clarifying some formal and physical aspects that are usually not covered by the standard pedagogical literature. The non-conventional approach adopted starts by showing that the continuum limit, in certain cases, cancels out the crucial…

Electrochemical cell potentials have no simple relationship with temperature but depend on the interplay between the sign and magnitude of the isothermal temperature coefficient, dE[degrees]/dT, and on the magnitude of the reaction quotient, Q. The variations in possible responses of standard and non-standard cell potentials to changes in the…

One of the oldest yet interesting experiments related to heat and thermodynamics is placing a string on a block of ice and hanging two masses from the ends of the string. Sometime later, it is discovered that the string has passed through the ice without cutting it in half. A simple explanation of this effect is that the pressure caused by the…

To most students today the mechanical equivalent of heat, called the Mayer-Joule principle, is simply a way to convert from calories to joules and vice versa. However, in linking work and heat--once thought to be disjointed concepts--it goes far beyond unit conversion. Heat had eluded understanding for two centuries after Galileo Galilei…

Though heterogeneous nucleation of liquid droplets on a smooth surface (such as a bathroom mirror) is a classical topic in nucleation theory, it is not well-known that this topic is actually a pedagogical example of heterogeneous catalysis: the one and only effect of the surface is to lower the activation Gibbs energy of droplet formation. In…

This undergraduate physical chemistry laboratory exercise introduces students to the study of probability distributions both experimentally and using computer simulations. Students perform the classic coin toss experiment individually and then pool all of their data together to study the effect of experimental sample size on the binomial…

A design exercise in chemical engineering is described which is concerned with thermocouples. Physics is the relevant discipline, a point that was made to the students doing the exercise, and accordingly an account of the exercise for the guidance of teachers and lecturers is presented as a contribution to "Physics Education."

A project that involves the numerical simulation of transport phenomena is an excellent method to teach this subject to senior/graduate chemical engineering students. The subject presented here has been used in our senior/graduate course, it concerns the study of natural convection heat transfer between two concentric, horizontal, saturated porous…

This study explored undergraduate students' understanding of the chemistry topic of thermodynamics using a 4-tier diagnostic instrument, comprising 30 questions, and follow-up interviews. An additional objective of the study was to assess the utility of the 4-tier instrument for use in studies on alternative conceptions (ACs) as there has been no…

Necessary and sufficient criteria for reaction spontaneity in a given direction and for spontaneity of finite transformations in single-reaction, closed systems are developed. The criteria are general in that they hold for reactions conducted under either conditions of constant T and p or constant T and V. These results are illustrated using a…