Offers a critique of the conventional approach to teaching of equilibrium in chemically reacting systems and outlines a more satisfactory approach. This approach is based not in kinetics but in the basic principles of thermodynamics. The approach is especially useful for the advanced student. (Author/JN)

Provides background information designed to aid a physical chemistry student in using the virial equation of state in deriving expressions for other thermodynamic properties, such as writing the Joule and Joule-Thomson coefficients in terms of virial expansions. (CS)

Laboratory procedures, calculations, and sample results are described for a freshman chemistry experiment in which the Clausius-Clapeyron equation is introduced as a means of describing the variation of vapor pressure with temperature and for determining enthalpy of vaporization. (Author/SK)

The chemical system of rubbery elasticity is presented. Several references are given from which to extract experiments and problems for students. (SA)

Describes the use of ethyl or methyl ethanoate mixed with trichloromethane to illustrate intermolecular forces and deviations from Raoult's Law. (MLH)

Describes an experiment in which chemistry students determine the efficiency of a laboratory burner used to heat water. The reaction is assumed to be the complete combustion of methane, CH4. The experiment is appropriate for secondary school chemistry students familiar with heats of reaction and simple calorimetry. Contains pre-laboratory and…

Studies the conceptual changes and factors affecting eighth- grade physical science students (n=180) investigating elementary thermodynamics. Classifies three types of students regarding their learning methods: converging, progressing, and oscillating. Reports that original intuitive conceptions are difficult to change and that students engaged in…

Demonstrates misconceptions of the meaning of temperature based on classical kinetic energy. Discusses some misconceptions about negative temperatures and the effect of compression. (YP)

Discusses the physical basis and current understanding of hydrophobic effects. The thermodynamic background of the effects, hydrophobic hydration, and hydrophobic interactions are described. Four existing controversies are outlined. (YP)

Discusses interesting aspects of the Carnot cycle and other thermodynamic cycles that are generally not dealt with in elementary physics texts. Presents examples that challenge the student to think about the extraction of net work from a cycle. (JRH)

Analyzes textbooks on thermodynamics with the aim of showing that several mental representations of this subject matter are present in scientific literature. Outlines divergent attitudes towards the definition of fundamental concepts and also towards the epistemological status of thermodynamics. Highlights the importance of historical…

Addresses the possible connection between misconceptions of energy in biological phenomena and adherence to scientifically oriented conceptions of biology. Makes recommendations for basing the biology curriculum on the second law of thermodynamics. Contains 31 references. (DDR)

Presents results of two teaching experiments at university level each involving five students. Attempts in the experiments to build on students' forms of energy language as well as to challenge its limitations. Describes student and teacher reasoning. Concludes that forms of energy language must be reformulated before it can be evaluated with…

Analyzes students' misunderstanding of basic thermodynamic concepts on historical grounds. Finds that the persistence of some ideas from the caloric model are reinforced by magnitude names and unit definitions that were brought up at the early stages of thermodynamic development. Explores the failure of many popular textbooks to make a clear…

Believes that a student's understanding of energy concepts can be enhanced by introducing and using the concept of internal energy by articulating the first law of thermodynamics in a simple, phenomenological form without mathematical encumbrances. (Author/CCM)