This paper describes an upper-division undergraduate exercise involving the synthesis and iodometric and infrared spectroscopic analysis of the peroxide double salt [Zn(NH[subscript 3])[subscript 4]][Mo(O[subscript 2])[subscript 4]]. Here, iodometric methods are employed to determine the peroxide content of the compound, a procedure widely used…

When we teach thermodynamics, a vacuum container used to keep food isolated from air is a cheap and interesting teaching device. There are some experiments already described in the literature and we can also find videos of demonstrations on YouTube. At the same time, there is increasing interest in how to utilize smartphones in physics…

Iodonium zwitterions are hypervalent iodine compounds in which the iodine center binds to two substituents and carries a positive formal charge which is compensated by a negative charge within the same molecule. Under thermodynamic conditions, iodonium zwitterion sallow concerted nucleophilic aromatic substitutions to be performed, followed by…

The effects of kinetic vs thermodynamic control on "endo"/"exo" stereoisomer ratios can be observed in a simple Diels-Alder reaction between "N"-phenylmaleimide and furan. The use of microwave-promoted synthesis affords the cycloadducts in yields ranging from 65-100%, employing reaction times of 1-10 min at…

An easy operating tool has been developed for the quick measurement of thermoelectric power. The setup is made using a tweezer which consists of two circular copper plate electrodes. These copper electrodes are fixed to two arms of the tweezer which act as hot and cold probes. The setup has the very important advantage of easy sample mounting and…

For 26 years, it has been assumed by some that the thermodynamics of open-system biochemical reactions must be executed by performing Legendre transformations on the terms involving the species whose concentrations are being held fixed. In contrast, standard nontransformed thermodynamics applies to chemical processes. However, it has recently been…

Assessments are an integral part of academic environments and can present opportunities for students to make sense of novel contexts using their existing ideas. Assessments also provide insights on students' learning and the efficacy of the pedagogical practices. Consequently, physics education research shares a storied history of developing…

The main purpose of this study was to describe the development and use of a flowchart for preservice chemistry teachers' problem solving on the First Law of Thermodynamics. Twenty-seven undergraduate preservice chemistry teachers attending a Physical Chemistry course participated in this study. The responses of the participants to the set of test…

Watching over a coffee maker in operation, and designing a simple experiment using it, invokes familiar and unfamiliar physical phenomena and techniques involving calorimetry and heat transfer.

Entropy is a concept with an extreme controversy which many scientists have been trying to explain. Some of the approaches employed in its definition contradict each other, which made it extremely difficult for high school and college students to understand. Boltzmann was the first person who brought a statistical explanation to entropy and…

[This paper is part of the Focused Collection in Artificial Intelligence Tools in Physics Teaching and Physics Education Research.] Using a high-stakes thermodynamics exam as the sample (252 students, four multipart problems), we investigate the viability of four workflows for AI-assisted grading of handwritten student solutions. We find that the…

Constructing causal mechanistic explanations of observable phenomena is a key science practice that is often challenging for students as most mechanisms involve interactions of unobservable entities and activities. In this study, we examined how gesturing with a computer simulation that depicts the molecular mechanism of thermal conduction…

The Reaction Coordinate Diagram Inventory (RCDI) was developed to measure chemistry students' thinking and confidence when interpreting the kinetic and thermodynamic information encoded within reaction coordinate diagrams (RCDs). The RCDI was designed based upon analyses of qualitative data collected in semi-structured interviews with general…

This paper provides seven topics on sodium hydrogen carbonate (NaHCO[subscript 3]) and its ions for readers looking for familiar material phenomena to strengthen students' understanding of the chemical concepts of thermodynamics. The first concept is the ideal gas law, followed by the van't Hoff equation, Gibbs energy, pH change, chemical…

The need for online education continues to grow in many fields and disciplines driven by convenience and public health and safety concerns. Little is known about how online doctoral education affects the readiness of future faculty members to work and teach in university settings. This autoethnographic study explores the intentional socialization…