As an introduction to quadrupolar effects in NMR spectroscopy, students use low field ([superscript 1]H, 60 MHz), benchtop [superscript 13]C NMR spectroscopy to contrast the spin-spin coupling behavior of [superscript 13]C to the dipolar [superscript 1]H and quadrupolar [superscript 2]D in familiar solvents C(H/D)Cl[subscript 3], C(H/D)[subscript 2]Cl[subscript 2], and (C(H/D)[subscript 3])[subscript 2]CO. To explain the observations, students are introduced to the spin magnetic quantum number, I, and its use in predicting first order coupling patterns. To explain the multiplets, both the number of lines and the relative intensities, students must expand their understanding of coupling beyond the mnemonics "n + 1" and Pascal's triangle for binomial expansion and instead utilize the nuclear spin magnetic quantum number, I, for the quadrupolar nucleus [superscript 2]D. The exercise is a useful prelude to the introduction of NMR spectroscopy involving quadrupolar nuclei (e.g., [superscript 14]N (I = 1); [superscript 11]B (I = 3/2)) in upper-level inorganic chemistry courses or as a fundamental description of coupling in physical chemistry courses. An advantage of the low field spectrum ([superscript 13]C, 15 MHz) is the observation of magnetic nonequivalence of the two methyl groups in (CH[subscript 3])[subscript 2]CO in which the [superscript 13]C resonance for the methyl group is readily observed as a quartet of quartets.