The discovery of ferrocene, Fe(C[subscript 5]H[subscript 5])[subscript 2], in the 1950s sparked the development of organometallic chemistry including metallocene compounds. Shortly after the isolation of ferrocene, the analogous ruthenium and osmium compounds were discovered. The preparation of ferrocene is common in undergraduate inorganic…

Metal-organic frameworks (MOFs) are a class of porous materials that are often crystalline with high surface area and structural tunability. In this laboratory experiment designed for inorganic chemistry students at the undergraduate level, students complete a two-step experiment where they will first (i) synthesize two isostructural…

A two-component undergraduate laboratory experience has been developed by students in a senior level capstone course. The first component is a 3 h laboratory experience dedicated to the rapid synthesis of a metal-organic framework (MOF-808) in aqueous solution using readily available reagents and equipment. During the second component, MOF-808 was…

Course-based undergraduate research experiences (CUREs) are a promising approach for incorporating inquiry-based instruction into the undergraduate chemistry laboratory curriculum. This study used data from a national survey of inorganic chemistry faculty members (n = 142) to investigate CURE implementation in the inorganic chemistry instructional…

An integrated inorganic chemistry laboratory experience focusing on heterogeneous electrocatalysis with nickel (Ni)- and cobalt (Co)-based electrocatalysts is designed for upper-division, major-level chemistry students. In this laboratory, students will be guided through the fabrication of an indium tin oxide (ITO)-coated glass working electrode,…

Tungsten oxide semiconductors are used to photooxidize water. Students prepare WO3, CuWO4, and mixed composition thin film photoanodes. The syntheses are simple, allowing for the quick production of a range of materials. Photoanodes are tested in a photoelectrochemical cell assembled from common equipment, allowing for the direct comparison of…

A relatively large number of organic and inorganic chemistry reagents are air- or moisture-sensitive, and undergraduate students should be trained in their use. When handling such reagents, it is important to select the correct syringe and to use that syringe correctly. We have found that the best syringe for use in an undergraduate setting is a…

As ongoing digitalization accelerates the execution of experiments and the documentation and storage of the corresponding data substantially, appropriate research data management (RDM) is a necessity to enable sustainable research at all. Consequently, a rethinking is currently taking place in academia. This process becomes visible by the…

Capstone teaching laboratory activities can serve as a crucial part of the undergraduate learning experience. With this in mind, a laboratory activity that combines synthesis and multiple characterization techniques has been developed for an upper-division, laboratory-based inorganic course. Complexes of Cu(II) and Ni(II) of the amino acid glycine…

Simple, often artificial problems are normally preferred for introductory lab courses and are restricted to indoor participation. Microtitrations make it possible to leave the lab and study water chemistry directly in the natural environment. An exemplary outdoor challenge is presented here: travertine formation is context-rich, has to be examined…

Instructive, inexpensive, and environmentally friendly laboratory syntheses of two highly luminescent copper(I) complexes CuI(PPh[subcript 3])[subscript 2](py[superscript R]) (py[superscript R] = pyridine, 4-cyanopyridine) are described for second-year/upper-division undergraduate inorganic chemistry students. Both complexes exhibit bright…

The catalytic hydrogenation of alkenes and alkynes is an important part of the undergraduate chemistry curriculum and is a fundamental process in chemical industry. Inquiry-based laboratory activities are presented that investigate the hydrogenation of alkynes on a nanoparticle palladium surface to form alkenes, which go on to form alkanes. Alkyne…

A laboratory experiment that involves the synthesis, characterization, and application exploration of a metal-organic framework (MOF) has been developed for first-year undergraduates in the Faculty of Engineering at National University of Singapore. The desired MOF material was prepared from commercially available reagents in a facile…

The Leidenfrost nanochemistry synthesis of gold colloids was introduced in this "Journal" as an advanced method to synthesize gold nanoparticles during an undergraduate nanochemistry research project. When trying to repeat these experiments in the laboratory, we experienced difficulties in the synthesis of the gold nanoparticles since…

This work outlines the inadequacies of the "ions in a sea of electrons" model. Some general properties of metals are stated. A different "soft/flexible" sphere model is described. The benefits of using this other model to account for metallic properties are discussed. Equations based on the soft sphere model are used to…