Liquid metals are widely applied in various fields, including chemistry, catalysis, energy storage, chemical sensing, and stretchable electronics, due to their unique deformabilities. However, their behavior under a rod or ring electrode has never been analyzed. Furthermore, research on the deformation behavior of eutectic Ga--In (EGaIn), the most…

Photochemical reactions are initiated by the absorption of light, triggering the chemical reactions and resulting in the formation of products. These reactions are generally performed using a freely available renewable source of energy-solar energy. Solar simulators mimic both the ultraviolet and visible regions of sunlight and hence can serve as…

The addition of a small excess of triethyl orthoformate to an alcoholic mixture of NiCl[subscript 2]·6H[subscript 2]O and triphenylphosphine (PPh[subscript 3]) results in an increase in the typical isolated yield of [NiCl[subscript 2](PPh[subscript 3])[subscript 2]] from below 50% to over 85%. The impact of water when present in the reaction…

An undergraduate laboratory experiment has been developed for the synthesis of a reactive cross-linker that is useful in various highly visual demonstrations of organic reactivity, click chemistry, and biobased polymer synthesis. A triazolinedione-based cross-linker, which is known as a useful reagent for click chemistry, can be obtained from…

The crystalline sponge method allows for direct and precise molecular structure determination of liquid and gaseous targets and thus has been recognized as a revolutionary breakthrough in crystallography. To expose undergraduates to this cutting-edge technique, we have developed a comprehensive laboratory experiment with reaction conditions and…

Understanding the basics of d-electron configuration and the spin state of coordination complexes are essential elements of undergraduate inorganic chemistry. However, students in these courses find it difficult to conceptualize the ideas. Here, we have developed an undergraduate laboratory experiment that allows students to systematically…

As quantum information science and technology (QIST) is becoming more prevalent and occurring not only in research labs but also in industry, many educators are considering how best to incorporate learning about quantum mechanics into various levels of education. Although much of the focus has been on quantum concepts in nonlab courses, current…

The [2 + 2] photocycloaddition reaction of olefins is an effective, atom-economical approach to produce cyclobutane compounds in organic synthetic chemistry, and they usually exhibit high regioselectivity and stereoselectivity. Here we devised a solid-state [2 + 2] photocycloaddition experiment that introduces senior undergraduate students with…

A student experiment that uses QuEChERS (quick, easy, cheap, effective, rugged, and safe) methodology for extraction and HPLC for quantitative determination of tocopherols from seeds and nuts is described here. Chromatographic separation is achieved by using a pentafluorophenyl stationary phase which gives enhanced separation of the tocopherols…

A new undergraduate organic laboratory experiment has been developed and implemented for the Ugi three-component synthesis of the topical anesthetic lidocaine with excellent atom economy. Paraformaldehyde, diethylamine, and 2,6-dimethylphenyl isocyanide were combined and conveniently stirred at room temperature for a week in methanol with acetic…

Mercury beating heart (MBH) is a well-known demonstration of redox processes. However, the development and application of the MBH system are significantly restricted due to its safety issues. Here, a direct current electric field-enabled gallium-based liquid metal heartbeat in a salt solution or alkaline solution is introduced as a demonstration…

A new undergraduate organic laboratory experiment has been developed for amide bond formation between biorenewable 2-furoic acid and either of two substituted piperazines to prepare medicinally relevant amide products using a procedure with industrial significance. The reactions proceeded smoothly under ambient conditions using the combination of…

The process of method development is at the heart of analytical chemistry, yet direct experimental experience with the process is rarely taught in the undergraduate laboratory. We report here an experiment that uses rapid, safe, and inexpensive paper-based microfluidics with cell phone detection in order to facilitate the development of a…

Polymer chemistry is an important subject in the undergraduate chemistry curriculum. It is required for ACS-certified degrees and significantly connects to real world issues like the plastic waste crisis. While some concepts of polymer chemistry can be incorporated into lecture courses, students' understanding of material properties and…

This three-part laboratory experiment investigates key aspects of the Buchwald-Hartwig amination cross-coupling reaction through guided-inquiry learning strategies. The first part of this experiment utilizes high-throughput experimentation techniques to reinforce, explore, and extend fundamental concepts that are represented in the classroom,…