Anaerobic respiration reactions are of fundamental importance to global biogeochemical cycling of elements. Yet, the idea that cellular respiration can occur not only in the absence of oxygen but also involve the oxidation of inorganic substrates (e.g., AsO[subscript 3 superscript 3-], Fe[superscript 2+], H[subscript 2], H[subscript 2]S,…

We describe the components and implementation of an activity for multivariable calculus featuring applications to the field of chemistry. This activity focuses on the isobaric thermal expansion coefficient found using partial differentiation of the volume of an ideal gas with respect to temperature as pressure is held constant. Broader goals of…

We explored chemical engineering students' approaches to learning, study-related burnout, and perceptions of peer and self-assessment in a challenging physical chemistry thermodynamics course. Cluster analysis revealed three learning profiles based on students' approaches to learning: students who scored high in both organised studying and the…

Background: This study posits that scaffolded team-based computational modeling and simulation projects can support model-based learning that can result in evidence of representational competence and regulatory skills. The study involved 116 students from a second-year thermodynamics undergraduate course organized into 24 teams, who worked on…

A laboratory experiment that exposes students to fundamental concepts in kinetics and statistical thermodynamics to study systems of great current interest in nanotechnology by employing a foundational technique in physical chemistry is described. A modified commercial flash photolysis spectrometer was used to study photoinduced isomerization…

Seeking to foster the learning process and encourage the active participation of undergraduate students, this work proposes a new methodology that involves integrating smartphones into the learning process under a simple and accessible approach to learning in Chemistry and Physics laboratories aiming at facilitating the learning of some chemical…

The effects of kinetic vs thermodynamic control on "endo"/"exo" stereoisomer ratios can be observed in a simple Diels-Alder reaction between "N"-phenylmaleimide and furan. The use of microwave-promoted synthesis affords the cycloadducts in yields ranging from 65-100%, employing reaction times of 1-10 min at…

This paper provides seven topics on sodium hydrogen carbonate (NaHCO[subscript 3]) and its ions for readers looking for familiar material phenomena to strengthen students' understanding of the chemical concepts of thermodynamics. The first concept is the ideal gas law, followed by the van't Hoff equation, Gibbs energy, pH change, chemical…

Learning thermodynamics requires understanding abstract topics such as entropy and spontaneity. Students tend to rely on metaphors and everyday meanings to reason about these topics. This study investigates how students explain dissolution and precipitation using the concepts of entropy and spontaneity. Students from general chemistry, physical…

A spreadsheet project that enables students to construct chemical potential vs temperature plots, [mu](T), of liquid and gaseous mercury and all three phases of diiodine and ammonia is presented. Statistical thermodynamics is used to determine the entropies of the substances in the gas phase. For the solid and liquid phases, students start with…

In our technology driven world today, it is extremely important to increase the science literacy of our non-science majors. At Stockton University, this goal is attempted to be accomplished through our General Studies courses. This paper describes a lab-based course in the General Studies curriculum, 'The Science of Ice Cream'. At Stockton…

Two-dimensional nuclear magnetic resonance (2D NMR) techniques are regularly used for the determination of RNA structures. In an effort to introduce advanced level students who are generally not acquainted with or exposed to these techniques, this work, which has been designed as a practicum, utilizes a combination of 2D NMR techniques to help…

Thermodynamic characterization of micelle formation from an ionic surfactant in aqueous solutions is a classic experiment in physical chemistry. The critical micelle concentration (CMC) and the degree of micelle ionization ([alpha)] can be directly obtained by conductimetry, then thermodynamic parameters ([delta]G[subscript m][superscript o],…

Infrared (IR) thermography renders invisible infrared radiation with intuitive coloration in images and videos taken of objects, reactions, and processes. Educators can take advantage of this technology to extend students' sensory perception of chemical reactions or processes that absorb or release heat in rich detail. In theory, IR thermography…

The Hofmeister series is a recurring trend that ranks ions' abilities to influence various aqueous processes in solution. Herein, a set of project-based experiments was developed for students in an upper-level physical chemistry laboratory to investigate the specific ion effects on the thermodynamics of caffeine partitioning between aqueous and…