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ERIC Number: EJ1443417
Record Type: Journal
Publication Date: 2023-Mar
Pages: 6
Abstractor: As Provided
ISBN: N/A
ISSN: ISSN-0021-9584
EISSN: EISSN-1938-1328
An Investigation of the Temperature Dependence of a Monomer-Dimer Equilibrium Using UV-Vis and [superscript 1]H NMR Spectroscopies
Laura M. Hancock; David J. McGarvey; Daniela Plana
Journal of Chemical Education, v100 n3 p1283-1288 2023
A laboratory experiment in which [superscript 1]H NMR and UV-vis spectroscopies are applied to probe the temperature dependence of a monomer-dimer equilibrium involving a cyclopentadienone derivative is described and discussed. Details of the data analysis for extraction of equilibrium constants from the raw experimental data from both techniques are provided, leading to the determination of thermodynamic parameters ([delta][subscript r]H° and [delta][subscript r]S°) via van't Hoff analysis. Fully analyzed datasets are provided in the Supporting Information to aid adaptation of the experiment or its use as a data analysis activity.
Division of Chemical Education, Inc. and ACS Publications Division of the American Chemical Society. 1155 Sixteenth Street NW, Washington, DC 20036. Tel: 800-227-5558; Tel: 202-872-4600; e-mail: eic@jce.acs.org; Web site: http://pubs.acs.org/jchemeduc
Publication Type: Journal Articles; Reports - Descriptive
Education Level: Higher Education; Postsecondary Education
Audience: N/A
Language: English
Sponsor: N/A
Authoring Institution: N/A
Grant or Contract Numbers: N/A