A convenient approach to obtain Lewis structures for compounds of the type YX[subscript n] involves first constructing a trial structure that satisfies the valence of the outer atoms (e.g.,1 bond for fluorine, 2 bonds for oxygen, and 3 bonds for nitrogen)and placing the molecular charge (if any) on the central atom. The second step involves…

A chemistry laboratory experiment is described to introduce undergraduate college students to membrane separation technology. This experiment combines a simple nanowire membrane fabrication and visually indicated molecule separation. The membrane is produced via coprecipitation synthesis followed by a filtration assembly process, which can be…

Valence shell electron pair repulsion theory (VSEPR) as explained in most textbooks predicts that substituents bonded to a central atom in AX[subscript n]E[subscript z][superscript c] species (A = main-group central atom, X = substituent, E = lone pair on central atom, c = charge) will change their X-A-X angles to bend away from the lone pairs.…

A new teaching resource comprised of raw X-ray diffraction data sets from crystallography experiments has been compiled. The aim of this resource is to provide a tool with which to plug the teaching gap between crystals and chemical structures present at various levels of education, as well as providing examples for early stage researchers and…

Biochemistry students at the introductory level easily comprehend the importance of energy-yielding oxidation and reduction biochemical processes, but nevertheless, they fight with words "oxidation" and "reduction" (and with the corresponding adjectives, "oxidized" and "reduced") applied in biochemistry…

The great development of high-throughput molecular biology techniques and the consequent generation of massive data have made Bioinformatics essential for undergraduate Bioscience students. The importance of this scientific discipline is evidenced by the huge number of specialized publications, tools, and databases available. Training in…

Representations in chemistry are the tools by which students, instructors, and chemists reason with chemical concepts that are abstract. Although representations are regularly used within the chemistry classroom, there is more to uncover regarding the ways students interact with representations when given chemistry tasks. This study aimed to…

Resonance is a fundamental chemistry concept first introduced to students in General Chemistry I, reintroduced in Organic Chemistry I, and then utilized throughout other higher-level chemistry courses. A molecule or ion can be said to exhibit resonance when it can be represented by two or more chemical structures (i.e., Lewis structures) that…

Nanoscience and technology research offer exciting avenues to modernize undergraduate-level General Chemistry curricula. In particular, spherical nucleic acid (SNA) nanoconjugates, which behave as "programmable atom equivalents" (PAEs) in the context of colloidal crystals, are one system that one can use to reinforce foundational…

Understanding organic reaction mechanisms can be a challenging task for many undergraduate students, particularly those who are nonchemistry majors, despite the fact that organic chemistry is a mandatory course for numerous science and engineering undergraduate programs. The selectivity of a reaction is largely determined by the distribution and…

Chemistry undergraduate curricula typically place Nuclear Magnetic Resonance (NMR) lectures under either Organic Chemistry or Spectroscopy courses, aiming for students to acquire basic knowledge for the determination of the structure of simple organic compounds. On the other hand, regarding laboratory practice, NMR is frequently disregarded by…

Molecular modeling can be used as an excellent teaching method for providing better insight into the mechanism of free radical reactions. Due to its highly visual nature, it can affect and improve students' perception and visualization of chemistry phenomena. The majority of chemistry students will know how to represent a reaction between two free…

This article highlights some of the challenges in explaining simple substituent effects on keto-enol equilibria, particularly to an undergraduate audience. Quantum-chemical calculations were performed to identify the role of intramolecular hydrogen bonding, inductive effects due to electron-withdrawing groups, and cross-conjugation on the…

The rise of virtual and online education in recent years has led to the development and popularization of many online tools, notably three-dimensional (3D) models and augmented reality (AR), for visualizing various structures in chemical sciences. The majority of the developed tools focus on either small molecules or biological systems, as…

The inductive effect is one of the very important concepts of electronic effects in organic chemistry. In traditional teaching methods, only the origin, transmission mode, and decay of the inductive effect are introduced briefly, which is not conducive to students' complete understanding of the inductive effect. This work developed a new method to…