This paper is the first part of a three-part project "How the principle of energy conservation evolved between 1842 and 1870: the view of a participant". This paper aims at showing how the new ideas of Mayer and Joule were received, what constituted the new theory in the period under study, and how it was supported experimentally. A…

The historical development of the classical postulates of the second law of Thermodynamics can be traced back to the book by Sadi Carnot, "Reflections on the motive power of fire." While unique in its own right and in some sense revolutionary, the book starts with an analogy between heat engines and waterwheels. Waterwheels were common engines of…

With this paper, our main aim is to contribute to the realisation of the chemical reactivity concept, tracing the historical evolution of the concept of chemical affinity that eventually supported the concept of chemical equilibrium. We will concentrate on searching for the theoretical grounds of three key chemical equilibrium ideas: "incomplete…

Teaching thermodynamics to undergraduate students is reduced to mere mathematical treatment of Gedankenexperimente based on two abstract fundamental postulates of thermodynamics. Attempts to remedy deficiencies of such courses with aims of taking the historical context into consideration in order to illustrate the importance of socioeconomical…

Traces the development of thermodynamics in physics, focusing on a strategy which enables students to grasp in a limited time and by means of simple calculus the main implications of the second law essential for everyday life (understanding operation of heat engines, refrigerators, heat pumps, district heating, and energy degradation). (JN)