Entropy and the second law of thermodynamics have long been identified as difficult concepts to teach in the physical chemistry curriculum. Their highly abstract nature, mathematical complexity and emergent nature underscore the necessity to better link classical thermodynamics and statistical thermodynamics. The objectives of this systematic…

It is natural to interpret entropy as a measure of energy dispersion. However, the classical, phenomenological introduction to the topic, which relies on detailed analysis of Carnot engines, obscures this interpretation. Here, we propose a modification of the classical approach, which allows the basic properties of entropy to be proven without…

Energy conversion devices such as fuel cells, metal-air batteries, and electrolyzers have been envisaged as possible solutions for cutting down the continuous accumulation of greenhouse gases resulting from the combustion of fossil fuel. The bottleneck reaction for these devices is the oxygen reduction reaction (ORR) occurring at the cathode. The…

An activity is described that uses simple materials and an easy-to-perform protocol to estimate the Curie temperature of nickel, which is the temperature at which nickel loses its ferromagnetism. To do so, an object made of nickel metal is heated with a lighter until it loses its ferromagnetism. The metal is allowed to drop into a beaker that…

Historically, classical thermodynamics was developed during attempts to improve the efficiency of steam engines. Those investigations led to the well-known zeroth, first, and second laws of thermodynamics. Although these laws are presented independently, linkages between the zeroth and second laws have been pointed out in the physics teaching…

In this paper, a very simple and low-cost setup design is described for the Seebeck coefficient measurement of the disc and rod-shaped specimens. The setup has been tested for its reliable working by measuring the Seebeck coefficients of standard samples; measured values match with the literature. The setup can be built with commonly available raw…

This paper starts with an introduction to the concept of momentum current. It is followed by a discussion of its strength and density with the aid of several analogies made between momentum current and electric current. Based on the novel concepts of thermal charge and its quantity (entropy), the analogies are extended to entropy current. The…

In this work, we venture to show how careful use of a program for quantum chemical calculations (such as VASP) may enrich teaching in solid-state chemistry and how principles of thermodynamics contribute to a validation of phase diagrams and reaction pathways using the quasiternary system Li[subscript 2]O-Al[subscript 2]O[subscript…

The motivation, philosophy, and organization of a course on artificial intelligence in chemical engineering is presented. The purpose is to teach undergraduate and graduate students how to build AI-based models that incorporate a first principles-based understanding of our products, processes, and systems. This is achieved by combining…

We use the Survey of Thermodynamic Processes and First and Second Laws-Long, a research-based survey instrument with 78 items at the level of introductory physics, to investigate introductory and advanced students' difficulties with internal energy, work, and heat transfer. We present analysis of data from 12 different introductory and advanced…

The use of the thermodynamic formalism in the investigation of biochemical reactions constitutes one of the key analysis in bioenergetics, and the first step in such analysis is the selection of the adequate reference state. For biochemistry majors, thermodynamic analysis based on the chemical reference state is used in Physical Chemistry courses,…

The article describes research work that can help students observe and experimentally research the effects caused by the emission component of the filament current in fluorescent lamps' cathodes. When analysing the work of electronic devices--multi-purpose lamps that use thermionic emission--research usually focuses on the current caused by the…

Analogies can be powerful teaching tools because they can make new material intelligible to students by comparing it to material that is already familiar. In assisting students to understand chemistry concepts, teachers occasionally use analogies. These analogies are believed to help the students to structure the new knowledge and they are…

Teaching and learning introductory thermodynamics has drawn considerable research attention over the last two decades, especially in several disciplines of higher education. Under particular investigation is the First Law of Thermodynamics (FLT), which offers an expression of energy conservation in thermodynamic systems, as the evidence shows that…

The distinction between pressure in a liquid and in a gas is often treated in a cursory way, or not treated at all, even in university level textbooks. Most texts fail to point out the relation between pressure and density in a gas as compared to pressure in a--virtually incompressible--liquid. In many instances this also results in a dismissive…