Keto-enol tautomerization is paramount to understanding the mechanisms involved in many organic reactions and biochemical transformations. Isomerization of an enol to a carbonyl compound is typically introduced during the discussion of the acid-catalyzed electrophilic addition of water to alkynes. The tautomerization of carbonyl compounds to enol…

Entropy and the second law of thermodynamics have long been identified as difficult concepts to teach in the physical chemistry curriculum. Their highly abstract nature, mathematical complexity and emergent nature underscore the necessity to better link classical thermodynamics and statistical thermodynamics. The objectives of this systematic…

Under the appropriate conditions, oscillatory chemical reactions have the capacity to generate chemical waves and spatial patterns. Among these structures, Turing patterns are a distinct class that, to date, has not been commonly demonstrated in a classroom environment. We present here a novel, practical procedure for the demonstration of Turing…

Energy conversion devices such as fuel cells, metal-air batteries, and electrolyzers have been envisaged as possible solutions for cutting down the continuous accumulation of greenhouse gases resulting from the combustion of fossil fuel. The bottleneck reaction for these devices is the oxygen reduction reaction (ORR) occurring at the cathode. The…

Anaerobic respiration reactions are of fundamental importance to global biogeochemical cycling of elements. Yet, the idea that cellular respiration can occur not only in the absence of oxygen but also involve the oxidation of inorganic substrates (e.g., AsO[subscript 3 superscript 3-], Fe[superscript 2+], H[subscript 2], H[subscript 2]S,…

We describe the components and implementation of an activity for multivariable calculus featuring applications to the field of chemistry. This activity focuses on the isobaric thermal expansion coefficient found using partial differentiation of the volume of an ideal gas with respect to temperature as pressure is held constant. Broader goals of…

An activity is described that uses simple materials and an easy-to-perform protocol to estimate the Curie temperature of nickel, which is the temperature at which nickel loses its ferromagnetism. To do so, an object made of nickel metal is heated with a lighter until it loses its ferromagnetism. The metal is allowed to drop into a beaker that…

In this laboratory experiment, students modify a series of surfaces and explore the effects of varying surface chemistry and texture on wettability by different probe liquids. Students begin by building a simple contact angle goniometer utilizing their mobile phone cameras. Next, they contrast the wettability of planar glass substrates…

Under most conditions, a liquid mixture does not have long-range structural order and may be considered to be a homogeneous collection of molecules in random motion. However, if a single-phase critical mixture of a partially miscible liquid--liquid system is subjected to a small temperature jump into the two-phase region, then structural coherence…

Thermodynamics education is not easy both for students and teachers. But the Entropy, Chemical potential, Real gas structure, Fugacity, Molecular interaction, Supercritical phenomena chapters become more comprehensible, if introduced via the pure real gases' cluster physics chapter. A pure gas consists of the only one type of basic particles,…

The fundamental principles and applications of thermodynamics and single-component phase equilibrium are used to explain and quantitatively analyze the operation and performance of the vapor-compression refrigerator (VCR). Carbon dioxide is used as the refrigerant. The four processes (or steps) that comprise the VCR refrigeration cycle are…

Analogies can be powerful teaching tools because they can make new material intelligible to students by comparing it to material that is already familiar. In assisting students to understand chemistry concepts, teachers occasionally use analogies. These analogies are believed to help the students to structure the new knowledge and they are…

Recent progress in elucidating chemical reactions allows to explain chemistry by the potential energy of the involved chemical structures. Nevertheless, from an educational point of view, empirical results indicate that students often do not connect the core idea of energy with other chemical concepts. From a resource-oriented perspective,…

Redox reactions and their balancing are one of the basic chemistry subjects in which students may experience remarkable learning difficulties at the beginning of their university career. This topic represents an evolution of stoichiometry concepts related to the balancing of chemical reactions and can be taught with different approaches as a…

Millions of people do not have access to clean drinking water; thus, cost-efficient water treatment systems are vital. Chemists, environmentalists, technicians, and engineers will be the professionals making breakthroughs in this industry. This laboratory experiment aims to introduce undergraduate students to the removal of pollutants from water…