The teaching of quantitative genetic variation in the undergraduate laboratory practical environment can be difficult as, for quantitative phenotypes that are under the control of multiple loci, detection of phenotypic differences caused by individual variants is problematical without large samples, impractical in such classes. Pet dogs provide a…

Biodiesel is an important alternative fuel synthesized by the trans-esterification of vegetable oils, animal fats, and recycled greases. In this experiment, students prepared biodiesel through the base-catalyzed trans-esterification of several vegetable oils, which were subsequently analyzed in comparison with conventional petroleum-based fuels to…

Take-home examinations were utilized during the COVID-19 pandemic for upper-level analytical chemistry lecture courses. The questions were often scenarios which required the students to determine the best type of instrument to use and how to go about the experiment. Answers submitted were well thought out and detailed, showing that the students…

Thermodynamic characterization of micelle formation from an ionic surfactant in aqueous solutions is a classic experiment in physical chemistry. The critical micelle concentration (CMC) and the degree of micelle ionization ([alpha)] can be directly obtained by conductimetry, then thermodynamic parameters ([delta]G[subscript m][superscript o],…

The free radical chlorination of an alkane experiment is often used in the undergraduate laboratory curriculum to introduce students to the free radical mechanism, substituent effects, intermediate stability, and the relative reactivity of radicals. In this experiment, students monochlorinate multiple alkanes and analyze the reaction mixture using…

Keto-enol tautomerism is a special example of structural isomerism. In this experiment, 6-chlorofulvene is predominantly yielded during the chlorination reaction of 6'-hydroxyfulvene with POCl[subscript 3] in the presence of DMF. The high regioselectivity of this reaction is dominated by intramolecular hydrogen-bonding and steric hindrance,…

The COVID-19 pandemic has resulted in a need for social distancing measures in public spaces and will have an important impact on university level teaching going forward. Remote methods to complete laboratory related activities are a potential means of students achieving practical credit while still isolating or social distancing. We outline the…

The rapid transition in teaching format due to COVID-19 gives rise to many challenges, especially for research and lab activities since they may require a different approach with more constrained resources compared with lecture-based courses, in which various virtual communication platforms have now been employed. As essential parts for student's…

Loss of 7 weeks of organic chemistry laboratory work, including 3-4 weeks that would have been used for a CURE, prompted the creation of a literature review project in which students investigated synthetic routes to drug molecules of molecular weight 180 g/mol or less. The students wrote a 5-10 page paper and then made videotaped presentations…

In this brief experiment, students create a superhydrophobic surface as an application of polar--nonpolar interactions and redox chemistry. Half of a zincgalvanized steel strip is coated in copper nanoparticles through electroless deposition. A layer of nonpolar octadecanethiol is added to half of that copper surface. Students classify the three…

Experimental electrochemistry offers unique opportunities for interactive instruction at all levels of education; however, widespread adoption in curricula is hindered by high costs associated with electrochemical instrumentation. Thus, the development of affordable instruments represents an essential step toward making electrochemistry accessible…

A laboratory activity is described for senior high school or first year undergraduate level students that illustrates key concepts linked to extractive metallurgy. This experiment demonstrates preferential binding of a methoxyphenolic oxime ligand to Cu[superscript 2+] in the presence of other transition metal ions in aqueous solution. The…

Infrared (IR) thermography renders invisible infrared radiation with intuitive coloration in images and videos taken of objects, reactions, and processes. Educators can take advantage of this technology to extend students' sensory perception of chemical reactions or processes that absorb or release heat in rich detail. In theory, IR thermography…

On the basis of recent advances in battery research and technology, we have developed a novel laboratory exercise centered on an organic--inorganic battery using the redox chemistry of the organic molecule anthraquinone-2,7-disulfonic acid disodium salt (AQDS). Although most commercially available batteries are based on inorganic redox couples,…

This laboratory experiment allows one to study the effect of temperature in the process of formation of hydrogen bound cyclic dimers of benzoic acid (BA). The implementation of the proposed methodology, which comprises the use of FTIR spectroscopy and quantum chemistry calculations, enables the obtaining of the thermodynamic parameters of the…