Reactions between metal carbonates from d[superscript 5] to d[superscript 10] systems and glutamic acid are used to obtain molecular metal complexes and metal-organic frameworks (MOFs). When the ligand is an amino acid, these MOFs belong to the BioMOF class (metal-organic frameworks for biological and medical applications). The metal carbonates of…

Teaching symmetry point groups to introductory inorganic chemistry students is often complicated by the difficulties students face with mental manipulation of complex molecules. Additionally, most textbooks provide practice in the form of random two-dimensional molecules or figures of little significance. As an alternative, an assignment is…

A symmetry activity using student-built models was developed in line with faculty-developed pedagogical goals and a collaborative learning framework. The activity took place in a 3-h laboratory portion of an upper-division inorganic chemistry course. It required students to identify symmetry elements for seven molecules using common 2D…

The discovery of ferrocene, Fe(C[subscript 5]H[subscript 5])[subscript 2], in the 1950s sparked the development of organometallic chemistry including metallocene compounds. Shortly after the isolation of ferrocene, the analogous ruthenium and osmium compounds were discovered. The preparation of ferrocene is common in undergraduate inorganic…

Metal-organic frameworks (MOFs) are a class of porous materials that are often crystalline with high surface area and structural tunability. In this laboratory experiment designed for inorganic chemistry students at the undergraduate level, students complete a two-step experiment where they will first (i) synthesize two isostructural…

Assessments that are open-ended and student-centered may be used to encourage formation of networks between prerequisite material and new course content thereby promoting meaningful learning. Creative Exercises (CEs) are assessments that allow multiple correct answers and do not penalize for incorrect statements thereby inspiring creativity. CEs…

An advanced research discovery laboratory course in inorganic chemistry has been developed to engage undergraduate students in authentic research experiences directly related to concepts and theory taught in the lecture portion of the course. The 12-week laboratory involves an initial 4 weeks of training experiments on inorganic/organometallic…

Potash, an essential raw material of the 18th century, used to be produced from the ashes of plants. Known since antiquity, it was in 1807 that Humphry Davy put an end to the decades-long controversy about its nature as a compound. The technology behind potash production was implemented in Brazil by the Portuguese naturalist Frei Velloso. The…

Utility value interventions (UVIs) are brief assignments designed to promote students' perceived utility value of the content they are learning. UVIs have been shown to improve students' academic performance in varying STEM courses; however, the use of UVIs in either chemistry courses or upper-level courses has not been well explored. This study…

In this experiment, students explore the synthesis and physical property characterization of the magnetic material strontium hexaferrite (SrFe[subscript 12]O[subscript 19]). SrFe[subscript 12]O[subscript 19] crystallites are prepared by a simple but fascinating sol-gel autocombustion synthesis. The prepared powder is compacted into pellets and…

A straightforward protocol for the preparation of the colorful and air-stable diphenyl ditelluride is described. In one laboratory session, students isolate their product and characterize it via melting point determination, mass spectrometry, and NMR spectroscopy ([superscript 1]H, [superscript 13]C­{[superscript 1]H}, and [superscript…

The teaching and learning of chemistry can be challenging due to the complex and abstract nature of the subject matter. Traditional methods of instruction often struggle to engage students and facilitate an understanding of essential chemical concepts. To address this, an innovative card game, "Compound Chain", was developed and…

Game-based learning has been shown to promote active learning. We have designed a card game termed CountQuest, played on the online platform Zoom, to facilitate the revision of the effective atomic number (EAN) concept for metal complexes previously taught in lectures. This game was played by undergraduate and graduate chemistry students during…

This report describes a laboratory experiment for an undergraduate-level inorganic chemistry or biochemistry course involving the study of the kinetics of the catecholase activity of a synthetic nickel­(II)-oximate complex. A model substrate, 3,5-di-tert-butylcatechol(DBC), undergoes aerobic oxidation to 3,5-di-tert-butylbenzoquinone (DBQ) in the…

Despite tremendous efforts by instructors and textbook authors, students find it difficult to develop useful chemical intuitions about structures and key properties of the important d-block organometallic species that have a d[superscript 6], d[superscript 8], or d[superscript 10] d-electron count. A full molecular orbital analysis is not always…