This is an easy and cheap experiment where chemistry Masters students can evaluate the role of some metal ions (i.e., Cu[superscript II] and Mn[superscript II]) in dopamine oxidation, related to Parkinsonism. The required prior knowledge is being familiar with the basis of UV-vis spectroscopy. Details of the activity, including procedure and…

Nitrogen gas dominates the Earth's atmosphere but is largely ignored. Molecular nitrogen is extremely stable and so nitrogen is termed inert. What would happen if another 'inert' gas were the dominant species instead of molecular nitrogen? Here we show how unique nitrogen is and how important it has been to life on planet Earth.

In this article we consider a well-known simple, very accessible demonstration of surface tension with a small boat propelled by substances that change the surface tension of water. A simple quantitative evaluation is provided that matches well with experimental data. A modification to the experiment is proposed allowing it to continue for a long…

Acid-base chemistry, and in particular the Lewis acid-base model, is foundational to understanding mechanistic ideas. This is due to the similarity in language chemists use to describe Lewis acid-base reactions and nucleophile-electrophile interactions. The development of artificial intelligence and machine learning technologies has led to the…

Molecular symmetry plays an important role in many areas of chemistry, and students are generally taught to identify intramolecular symmetries at the undergraduate level. Intermolecular symmetry, the symmetry among groups of molecules, is of great importance in topics such as X-ray crystallography, but it receives substantially less attention.…

Nanoparticle Zn[subscript 2x] Cu[subscript 1-x] In[subscript 1-x] S[subscript 2] is a promising and safer alternative to lead- and cadmium-containing quantum dots. Students prepare Zn[subscript 0.44] Cu[subscript 0.78] In[subscript 0.78] S[subscript 2] quantum dots in a one-pot synthesis without an inert atmosphere and investigate how the color,…

Polymers and nanochemistry are important facets of chemistry. In this experiment, students synthesize monodispersed poly(methyl methacrylate) nanospheres from the addition or chain polymerization of a rapidly stirred aqueous mini-emulsion of methyl methacrylate. The 2,2'-azobis(2-methylpropionamidine) dihydrochloride serves as a heat activated,…

Constructing causal mechanistic explanations of observable phenomena is a key science practice that is often challenging for students as most mechanisms involve interactions of unobservable entities and activities. In this study, we examined how gesturing with a computer simulation that depicts the molecular mechanism of thermal conduction…

Is the reductionist approach to teaching chemical principles in the laboratory adequate for students to make effective evaluations? In this work, using the example of sunscreens, students first assessed the analytical chemistry parameters of the active ingredients, later comparing and contrasting them with organic chemistry information for…

Introductory chemistry textbooks often present valence bond (VB) theory as useful, but incorrect and inferior to molecular orbital (MO) theory, citing the electronic structure of O[subscript 2] and electron delocalization as evidence. Even texts that initially present the two theories on equal footing use language that biases students toward the…

Nuclear magnetic resonance (NMR) spectroscopy is the tool of choice for organic chemists to determine the molecular structure of organic molecules and, as a result, is a fundamental topic in the organic chemistry curriculum. A novel laboratory module has been developed to expand the scope of NMR spectroscopy beyond structure validation at the…

An introduction to the noble gases and chemical bonding via Lewis theory and the octet rule are common inclusions in secondary school curricula. However, the usual approach may lead to misconceptions and difficulties when valence bond (VB) theory and valence shell electron pair repulsion (VSEPR) theory are taught at a later pre-university stage.…

Understanding redox reactions in biochemistry requires a clear grasp of three definitions: electron exchange, oxidation number, and oxygen atom insertion. Here, the electrochemical cell is explained for redox-active ions, introducing a new comparison between the measurement of midpoint potential and the measurement of initial velocity for enzymes.…

Electromagnetic radiation can be classified into two major types depending on its ability to detach electrons from atoms: ionising and non-ionising. The aforementioned categorization is significant due to the effects of ionising radiation on human tissue (e.g. carcinogenesis). However, many students around the globe cannot distinguish these two…

Solutions to global issues demand the involvement of scientists, yet concern exists about retention rates in science as students pass through school into University. Young children are curious about science, yet are considered incapable of grappling with abstract and microscopic concepts such as atoms, sub-atomic particles, molecules and DNA.…