Studies the polarization effect on water by cations and anions. Describes an experiment to illustrate the polarization effect of sodium, lithium, calcium, and strontium ions on the water molecule in the hydration spheres of the ions. Analysis is performed by proton NMR. (MVL)

Describes a laboratory experiment designed to encourage laboratory cooperation among individual undergraduate students or groups. Notes each student contributes results individually and the exchange of data is essential to obtain final results. Uses the polarographic method for determining complex metal ions. (MVL)

Presents two experiments: the first one measures the heat of an exothermic reaction by the reduction of permanganate by the ferris ion; the second one measures the heat of an endothermic process, the mixing of ethanol and cyclohexane. Lists tables to aid in the use of the solution calorimeter. (MVL)

Describes an analytical technique termed the "thermostatic method" that is both conceptually and operationally simple and does not require the removal of liquid samples for analysis. Presents the theoretical background, experimental procedures, and analysis of results. (CW)

Describes experiments in which students prepare in situ soluble complexes of metal ions with different ligands and observe and estimate the change in formal potential that the ion undergoes upon complexation. Discusses student formation and analysis of soluble complexes of two different metal ions with the same ligand. (CW)

Describes a laboratory exercise in which acid dissociation constants and molecular weights are extracted from sample data and the sample is identified. Emphasizes accurate volumetric work while bringing to practice the concepts of acid-base equilibria, activity coefficients, and thermodynamic constants. (CW)

Describes an application of potentiometry to the determination of acidic and basic compounds in household cleaners in chemistry instruction. Discusses procedures and results of this experiment. (CW)

Suggests a laboratory introduction to solid-solid phase transitions, thermochromism, and color changes associated with changes in ligand coordination suitable for undergraduate students in physical and general chemistry. Describes the preparation and analysis of the experiment. (CW)

Describes an apparatus that can be used to measure low gas pressures over a range of temperature in the undergraduate teaching laboratory. Discusses an experimental procedure and theory for pressure temperature measurements with this apparatus. (CW)

Describes a series of laboratory experiments designed to provide concrete experiences with advanced inorganic chemistry lecture topics. Stresses student invention of chemical relationships and periodicity according to physical properties and reaction type. Includes comments on student performance and attitudes toward the experiments. (JM)

Describes a physical organic experiment in thermodynamics and kinetics for undergraduate courses in organic chemistry, biochemistry, or physical chemistry. Details background information, solution preparations, equipment and methods, and the suggested experiments such as determination of general-base-catalytic coefficients and the Bronsted…

Describes two introductory exercises designed to teach the fundamental ideas and methods of crystallography, and to convey some important features of inorganic and organic crystal structures to students in an advanced laboratory course. Exercises include "The Crystal Structure of NiO" and "The Crystal Structure of Beta-Fumaric Acid." (CW)

Describes a project that can be used to encourage intellectual independence in students and teach them some of the inquiry procedures used in scientific research. Discusses procedures, safety precautions, and sample results. (CW)

Provides a prospective on electrosynthesis technology for chemical educators and students by discussing electrosynthesis reactions and experiments. Includes tables illustrating some electrochemical products, variables to consider in electrochemical reactions, indirect electrolysis of organic compounds, examples of direct/indirect electrochemical…

Provides the methodology put forth by Moore and Kraus to separate Co++ from Ni++ in an 8M HCl solution. Notes that cobalt(II) forms a wide variety of anionic complexes. Points out that as the solutions leave the exchange column the color bands of green, blue, and pink are easily seen. (MVL)