An experimental apparatus was designed and built to allow students to carry out heat conduction experiments in hollow cylinders made of different materials, as well as to determine the thermal conductivity of these materials. The evolution of the temperature difference between the inner and outer walls of the cylinder as a function of time is…

Measurements have been added to an old demonstration of chemical equilibria allowing the determination of thermodynamic constants. The experiment allows the students an opportunity to merge qualitative observations associated with Le Chatelier's principle and thermodynamic calculations using graphical techniques. (Contains 4 figures.)

Differential scanning calorimetry analyses of two easily prepared polymorphs of acetaminophen (also known as paracetamol) are recorded. The density of the forms can be found in the literature. Rules for heats of transition, heats of fusion, and density, as well as methods for determining the solid-solid transition temperature between the forms,…

This paper deals with subtleties and misunderstandings regarding the Clausius relation. We start by demonstrating the relation in a new and simple way, explaining clearly the assumptions made and the extent of its validity. Then follows a detailed discussion of some confusions and mistakes often found in the literature. The addressed points…

Comparing the predicted and actual rolls of combinations of both two and three dice can help to introduce many of the basic concepts of statistical thermodynamics, including multiplicity, probability, microstates, and macrostates, and demonstrate that entropy is indeed a measure of randomness, that disordered states (those of higher entropy) are…

Thermoacoustic instability can appear in any thermal device when the unsteady heat transfer is favourably coupled with the fluctuations of acoustic pressure. In this paper, we present a project type of physical measuring and modelling task; the aim of our project is to help our students increase their knowledge of thermoacoustics. Our paper…

Nearly 50 years ago, Henry Bent published his groundbreaking article in this "Journal" introducing the "global" formulation of thermodynamics. In the following years, the global formulation was elaborated by Bent and by one of the present authors. The global formulation of the first law focuses on conservation of energy and the recognition that…

This paper addresses a controversy regarding the effect of bottle material on the thermal performance of beverage bottles. Experiments and calculations that verify or refute advertising claims and represent an interesting way to teach heat transfer fundamentals are described. Heat transfer coefficients and the resistance to heat transfer offered…

Two experiments are proposed to study Boyle's law and the pressure law in a school laboratory. The peculiar feature of the experiments is that the value of the pressure and of the volume are obtained respectively by means of a force and a position sensor, thus allowing students to connect, in an experimental context, mechanics variables, such as…

The four-week student project described in this article is an extension of protein thermal denaturation experiments to include effects of added cosolutes ethylene glycol, glycine betaine, and urea on the unfolding of lysozyme. The transition temperatures and van't Hoff enthalpies for unfolding are evaluated for six concentrations of each cosolute,…

The temperature dependence of the dielectric permittivity is taken into account to study the energy change in a capacitor that follows a cycle between a cold and a hot thermal reservoir. There is a net energy gain in the process that, in principle, can be transformed into usable work. The paper is simple enough as to be used with keen…

In this paper we address a common misconception concerning the thermal behaviour of matter, namely that the front surface of a very thin plate, uniformly illuminated by a constant light beam, reaches a higher temperature than the front surface of a very thick slab made out of the same material. We present analytical solutions for the temperature…

Background and purpose: The aim of this study was to explore the effect of investigative activities with manipulations in a virtual laboratory on students' ability to design experiments. Sample: Fourteen students in a lower secondary school in Greece attended a teaching sequence on thermal phenomena based on the use of information and…

We developed a modular pair of experiments for use in the undergraduate physical chemistry and biochemistry laboratories. Both experiments examine the thermodynamics of the binding of a small molecule, eosin Y, to the protein lysozyme. The assay for binding is the quenching of lysozyme fluorescence by eosin through resonant energy transfer. In…

The rapid compression or expansion of a gas in a plastic syringe is a poor approximation of an adiabatic process. Heat exchange with the walls of the syringe brings the gas to equilibrium in an amount of time that is not significantly greater than the length of the compression or expansion itself. Despite this limitation, it is still possible to…