Describes an experiment using a high-speed preparative centrifuge and calculator to demonstrate effects of the frictional coefficient of a macromolecule on its rate of transport in a force field and to estimate molecular weight of the macromolecule using an empirical relationship. Background information, procedures, and discussion of results are…

Describes a method, using simple algebraic notation, for calculating the nature of the salient features of a sugar pyranoid ring, the steric disposition of substituents about the reference, and the anomeric carbon atoms contained within the ring. (CS)

Presents and discusses a procedure for estimating the dissociation energies of diatomic molecules by taking into account experimentally observable parameters. (CS)

Selected infrared laser chemistry topics are discussed including carbon dioxide lasers, infrared quanta and molecules, laser-induced chemistry, structural isomerization (laser purification, sensitized reactions, and dielectric breakdown), and fundamental principles of laser isotope separation, focusing on uranium isotope separation. (JN)

Presents a discussion of the early developments in the field of quantum chemistry. (BB)

Describes plastic, skeletal molecular models that are color-coded and can illustrate both the conformation and overall shape of small molecules. They can also be converted to space-filling counterparts by the additions of color-coded polystyrene spheres. (MLH)

Presents an activity in which students gather their own snowflake collection in search of matching crystals. Students stretch plastic wrap over embroidery hoops that provide a snowflake-catching surface. Snowflakes are viewed under a microscope and photographed. (MDH)

An experiment to prepare a deuterium labeled adduct of a Lewis acid and Lewis base, to use computational methods allowing students to visualize the LUMO of Lewis acids, the HOMO of Lewis bases and the molecular orbitals of the adduct that is formed is developed. This allows students to see the interplay between calculated and experimental results.

The quantity of information available on Co(III)-pentaammine complexes to the undergraduate students is based on their dissociatively activated substitution processes. The advanced undergraduate set of experiments is presented that fill an important gap in the understanding of the differences taking place in the substitution mechanisms operating…

Describes how to construct a model of a DNA molecule with inexpensive materials. (BR)

Discusses various interpretations of the concept of chemical valence and describes a method for correlating bond length with valence. (MLH)

Describes ways that students can construct molecular models from fishing-tackle materials. (MLH)

Describes an inexpensive, easily constructed model of the right-handed alpha-helix, consisting of cardboard, plastic tubing and a wooden support. (MLH)