Modifications are presented for the iodine clock reaction to introduce the concept of activity and to help students better appreciate molecular aspects of chemical equilibrium. The addition of an unreactive salt affects the activity of the reactants in the iodine clock reaction. The difference in activity affects how long the iodine clock reaction…

A convenient approach to obtain Lewis structures for compounds of the type YX[subscript n] involves first constructing a trial structure that satisfies the valence of the outer atoms (e.g.,1 bond for fluorine, 2 bonds for oxygen, and 3 bonds for nitrogen)and placing the molecular charge (if any) on the central atom. The second step involves…

As a widely applied theory that has found success across many fields, density functional theory (DFT) is largely taught. Typically, the most effective way to convey DFT concepts is through illustrative examples that are currently lacking in available resources. In this work, we demonstrate total energy calculations for H[subscript 2] using…

A new teaching resource comprised of raw X-ray diffraction data sets from crystallography experiments has been compiled. The aim of this resource is to provide a tool with which to plug the teaching gap between crystals and chemical structures present at various levels of education, as well as providing examples for early stage researchers and…

Climate change is a critical scientific and social issue of our time, yet the topic is not frequently discussed by the general public. Additionally, misconceptions about the topic persist. One important aspect of climate change is the greenhouse effect. This activity adds a greenhouse gas discussion to an existing module about molecular shape and…

Most chemistry instruction and assessment lie in the symbolic domain of Johnstone's representational levels, despite years of chemistry education researchers calling for increased emphasis to be placed on the molecular or particulate level of chemistry. Without a deep understanding of the particulate nature of matter and molecular-level…

A mixture of salt water and isopropyl alcohol is immiscible, forming two separate liquids with the organic layer on top and aqueous layer on bottom. When universal indicator is added to such a mixture, all of the indicator compounds in the universal indicator preferentially dissolve in the alcohol--except for phenolphthalein at high pH. Mixtures…

Benzoin, an [alpha]-hydroxy ketone, is stereoselectively reduced by sodium borohydride to yield hydrobenzoin, the stereochemistry of which is determined by acetalization and analysis of the derivative by NMR spectroscopy. This classical experiment has been enhanced by modern spectroscopic and computational analysis to enable students to…

Traditional physical chemistry conceptions of reaction mechanism are formulated in terms of stationary points of an Arrhenius-style "energy profile" that differs sharply (in purpose and form) from the corresponding Robinson-style "arrow-pushing" mechanistic conceptions of organic chemistry. We show here how these diverse…

This investigation of student and instructor representations of molecular orbitals (MOs) uses the knowledge from a community of practice to build collective pedagogical content knowledge of student understanding of molecular orbital representations in the foundation-level inorganic chemistry course. Participants were asked to sketch the bonding…

This article presents computational chemistry exercises that are designed to be incorporated into an undergraduate physical chemistry course. This activity teaches computational chemistry as it is performed in higher-level research (in a command-line environment and executed on a high-performance computing cluster) to provide students with a…

The introduction of Computational Chemistry via "Molecular Modelling and Drug Design" course at undergraduate level has opened wide possibilities for students to expand their knowledge of quantum chemistry, organic reaction mechanisms, protein-ligand interactions, drug design, and probable "in vivo" behavior of drug candidates.…

The classic silver mirror reaction at room temperature in textbooks usually used glucose to react with silver nitrate and ammonium nitrate with the presence of caustic alkalis. But the aldehydes such as acetaldehyde and propionaldehyde were difficult to react under the same condition. In this paper, Na[subscript 2]CO[subscript 3] was used to…

Molecular modeling can be used as an excellent teaching method for providing better insight into the mechanism of free radical reactions. Due to its highly visual nature, it can affect and improve students' perception and visualization of chemistry phenomena. The majority of chemistry students will know how to represent a reaction between two free…

In recent years, chemistry educators are increasingly adopting immersive virtual reality (IVR) technology to help learners visualise molecular interactions. However, educational studies on IVR mostly investigated its usability and user perceptions leaving out its impact on improving conceptual understanding. If they evaluated students' knowledge…