Presents an experimental example illustrating the most common methods for the determination of kinetic parameters. Discusses the different theories and equations to be applied and the mechanism derived from the kinetic results. (CW)

Illustrates an interesting biomedical application of adsorption from solution and demonstrates some of the factors that influence the in vivo adsorption of drug molecules onto activated charcoal. Uses acetaminophen and N-acetylcysteine for the determination. Suggests several related experiments. (MVL)

Describes several experiments using the techniques of thermal analysis and thermometric titrimetry. Defines thermal analysis and several recent branches of the technique. Notes most of the experiments use simple equipment and standard laboratory techniques. (MVL)

Recommends determining molecular weights of liquids by use of a thermocouple. Utilizing a mathematical gas equation, the molecular weight can be determined from the measurement of the vapor temperature upon complete evaporation. Lists benefits as reduced time and cost, and improved safety factors. (ML)

Describes a molar volume-molar mass experiment for use in general chemistry laboratories. Gives background technical information, procedures for the titration of aqueous hydrogen peroxide with standard potassium permanganate and catalytic decomposition of hydrogen peroxide to produce oxygen, and a discussion of the results obtained in three…

Describes a laboratory experiment designed for use in a freshman chemistry course. Considers the use of a set of known "training reactions" with a "training set" of solutions. (CW)

Describes a two-session experiment designed to provide a good illustration of, and to improve student knowledge of, the Grignard reaction and nucleophilic substitution. Discusses the procedure, experimental considerations, and conclusion of this experiment. (CW)

Shows how video recordings of the Brownian motion of tiny particles may be made. Describes a classroom demonstration and cites a reported experiment designed to show the random nature of Brownian motion. Suggests a student experiment to discover the distance a tiny particle travels as a function of time. (MVL)

Offers challenging work at a higher level of technique than most students meet in elementary laboratory work. Uses a combined weight and volumetric sequence not shown in textbooks. Notes modern rapid balances help lower evaporation loss during weighings. Discusses the balance, weights, and buoyancy considerations. (MVL)

Describes a crystallography experiment using both diffraction-angle and diffraction-intensity information to determine the lattice constant and a lattice independent molecular parameter, while still employing standard X-ray powder diffraction techniques. Details the method, experimental details, and analysis for this activity. (CW)

Discusses the need for student experiments involving the complete characterization of "unknown" inorganic compounds. Describes a project employing a complex metal compound. The compound contains six different components in both inert and labile complexions. Outlines the complete procedure and the preparation of the unknown compound. (TW)

Reported are the results of a survey conducted to identify which analytical methods are most commonly used in nonacademic analytical laboratories. Laboratory supervisors' ratings of various aspects of chemical education are included. (CW)

All analytical techniques depend on the use of calibration chemicals to relate analyte concentration to instrumental parameters. Discusses the preparation of standard solutions and provides a critical evaluation of available materials. Lists elements by group and discusses the purity and uses of each. (MVL)

Describes several common synthetic organic transformations involving alkenes, alcohols, alkyl halides, and ketones. Includes concepts on kinetic versus thermodynamic control of reaction, rearrangement of a secondary carbocation to a tertiary cation, and the effect of the size of the base on orientation during elimination. (MVL)

Describes a laboratory experiment to teach the principles of air sampling, gamma ray spectroscopy, nuclear decay, and radioactive equilibrium. Analyzes radon by carbon adsorption and gamma ray counting. Provides methodology and rate of decay equations. (MVL)