A three-week laboratory project involving synthesis and characterization of a layered manganese oxide provides an excellent vehicle for teaching important concepts of inorganic chemistry and instrumental methods related to non-molecular systems. Na-birnessite is an easily prepared manganese oxide with a 7 A interlayer spacing and Na[superscript +]…

Describes a laboratory experiment designed to encourage laboratory cooperation among individual undergraduate students or groups. Notes each student contributes results individually and the exchange of data is essential to obtain final results. Uses the polarographic method for determining complex metal ions. (MVL)

Describes an advanced NMR project that can be done with a 60-MHz continuous-wave proton spectrometer. Points out the main purposes are to give students experience in second-order NMR analysis, the simplification of spectra by raising the frequency, and the effect of non-hydrogen nuclei on proton resonances. (MVL)

Describes a laboratory technique for quantitative analysis of caffeine by an isotopic dilution method for coupled gas chromatography-mass spectroscopy. Discusses caffeine analysis and experimental methodology. Lists sample caffeine concentrations found in common products. (MVL)

Attempts to show that in the closed loops of cyclic structures the protons situated in conic regions above and below the ring will be shielded. Uses the diamagnetic and air stable octahedral tin(IV) complexes of porphyrins for study. Notes complexes crystallize easily and offer spectacular purple colors. (MVL)

Discusses three aspects of electrochemical detectors: (1) signal and noise generation and signal-to-noise ratio, (2) improvement of qualitative information content, and (3) control of selectivity of the detector. Explains electronic principles of detectors and detection limits. Lists current applications and research. (ML)

Presents a low cost system with easily replaced electrodes for use in general chemistry. Notes the accuracy and wide applicability permit easy use in physical or quantitative chemistry experiments. Provides schematic, theory, and helpful suggestions. (MVL)

Discusses the need to encourage increasing numbers of persons to enter analytical chemistry, educate them thoroughly in basic chemical science, and expose them to the most modern methods and instrumentation. Examines some problems and several university's efforts to overcome them. (MVL)

Reported are the results of a survey conducted to identify which analytical methods are most commonly used in nonacademic analytical laboratories. Laboratory supervisors' ratings of various aspects of chemical education are included. (CW)

Discusses the history and development of Plasma Desorption Mass Spectrometry to determine molecular weights and structures of proteins and polymers. Outlines theory, instrumentation, and sample preparation commonly used. Gives several examples of resulting spectra. (ML)

Describes a technique for separating samples that range over 15 orders of magnitude in molecular weight. Discusses theory, apparatus, and sample preparation techniques. Lists several types of field-flow fractionation (FFF) and their uses: sedimentation FFF, thermal FFF, flow FFF, electrical FFF, and steric FFF. (ML)

Identifies a common laboratory problem that causes instrumentation malfunction. Provides numerous experiences of researchers whose results have been affected by humidity fluctuations, magnetic field fluctuations, trucks driving by, and other factors. (ML)

Discussed are four major advantages to the use of microscale laboratories for teaching chemistry. Included are effects on waste generation, laboratory safety, reagent variety, and laboratory efficiency. (CW)

Described are 14 experiments that use lasers. Topic areas include physical chemistry, analytical chemistry, organic chemistry, inorganic chemistry, and biochemistry. Instrumentation and the use of the laser in undergraduate research are discussed. (CW)

Discusses the use of robotics in the analytical chemistry laboratory. Suggests using a modular setup to best use robots and laboratory space. Proposes a sample preparation system which can perform aliquot measurement, dilution, mixing, separation, and sample transfer. Recognizes attributes and shortcomings. (ML)