Indicates that the concept of definite proportions or constant composition should be introduced with qualification. Presents arguments against the Law of Definite Proportions and cites examples in the areas of solid solutions, compounds of the transition and inner transition elements, and in some compounds of the representative elements. (GS)

Discusses an instructional strategy in which stoichiometric reactions are presented in terms of a recipe. Solutions for two different stoichiometric problems are included. (JN)

Reviews the history of the stoichiometric term "equivalent" and examines its relevance over the last hundred years. (MLH)

Describes an experiment presented to students as a problem in determining the stoichiometry of "copper iodide" to decide whether it is cuprous iodide or cupric iodide. The experiment illustrates stoichiometry principles, providing experiences with laboratory techniques and numerical computation. Detailed outline (written for student use) is…

Presents a solution to the problem of finding the source of extra reducing equivalents, and accomplishing the stoichiometry of glucose oxidation reactions. Discusses the citric acid cycle and glycolysis. (CW)

Discusses a method to solve problems in stoichiometry which can also be applied to other problems involving relationships between constituents in a chemical reaction. Students with little prior knowledge of chemistry can successfully use the method. (Author/SK)

The stoichiometry of the reaction between potassium chromate and barium chloride is determined by analysis of precipitates by mixing various amounts of both solutions. (GS)

Describes an experiment designed to augment textual materials conducive to the inquiry approach to learning. The experiment is the culminating experience in a series designed to illustrate the fundamental nature of the atom: its quantized energy nature, its electrical nature, and its combining ability. (Author/GS)

Describes an experiment in which possible products of a series of reactions are tabulated together with properties which may be useful in identifying each substance. The student deduces the products and writes a balanced chemical equation for the reaction. (GS)

Presents calculations that suggest stoichiometric, ionic, and noble gas-metal compounds may be stable. Bases calculations on estimated values of electron affinity, anionic radius for the noble gases and for the Born exponents of resulting crystals. Suggests the desirability of experiments designed to prepare compounds containing anionic,…

Reviews identified learning problems dealing with stoichiometric calculations. Suggests solutions to these problems along with consequences for the curriculum. Includes remarks from a mathematics teacher concerning these problems. (DS)

Describes a take-home exam story problem based on stoichiometry. Requires the student to determine the percentage of phosphoric acid in a large container of nitric acid if a man fell into it. Provides assumptions, clues, and an acceptable solution. (MVL)

Describes a method of flow injection analysis intended for calculation of complex-formation and redox reaction stoichiometries based on a closed-loop configuration. The technique is suitable for use in undergraduate laboratories. Information is provided for equipment, materials, procedures, and sample results. (JM)

Discusses problem-solving strategies and the successful strategy used to solve stoichiometric problems in general college chemistry courses. Reports that rereading problems, recalling a related concept, and reasoning deductively/inductively are the most heavily used strategies among 13 categories. (YP)

Describes a simple laboratory procedure for changing sodium carbonate into sodium chloride by adding concentrated HCl to cause the reaction and then evaporating the water. Claims a good stoichiometric yield can be obtained in one three-hour lab period. Suggests using fume hood for the reaction. (ML)