Starting with the fundamental and general criterion for a spontaneous process in thermodynamics, delta S[subscript tot] greater than or equal to 0, we review its relationships to other criteria, such as delta A and delta G, that have limitations. The details of these limitations, which can be easily overlooked, are carefully explicated. We also…

Nearly 50 years ago, Henry Bent published his groundbreaking article in this "Journal" introducing the "global" formulation of thermodynamics. In the following years, the global formulation was elaborated by Bent and by one of the present authors. The global formulation of the first law focuses on conservation of energy and the recognition that…

Argues that previous definitions of work and heat are inappropriate. Presents new definitions that are formulated using experimental quantities, claiming that they apply equally well to reversible and irreversible processes. Indicates some of the problems with earlier definitions and applies the new definitions to the First Law of thermodynamics.…