This report describes a laboratory experiment for an undergraduate-level inorganic chemistry or biochemistry course involving the study of the kinetics of the catecholase activity of a synthetic nickel­(II)-oximate complex. A model substrate, 3,5-di-tert-butylcatechol(DBC), undergoes aerobic oxidation to 3,5-di-tert-butylbenzoquinone (DBQ) in the…

This experimental lab set is for students taking college chemistry courses. It includes four laboratory works and completely illustrates the important parts of chemical kinetics, namely the determination of the rate constant and the determination of the factors influencing its value. They can be used in a laboratory set for a physical chemistry…

Oxygen reduction reaction (ORR),as a multielectron electrode reaction, is an important electrochemical reaction in the field of electrochemical energy storage systems. Herein, a new advanced electrochemical laboratory experiment is designed for undergraduates to master the preparation of oxygen reduction catalytic electrode. Students can use…

Scientific laboratories are among the most challenging course components to integrate into online instruction. Available technology restricts the design and nature of experiments, and it can be hard to replicate the collaborative lab environment where frequent and immediate instructor feedback is the norm. Here we report on technological and…

Cosmetic chemistry is a prevalent part of everyday life, but there are very few undergraduate laboratories that explore this topic. Here, we present a laboratory exercise in which students use fizzing bath tablets (better known as "bath bombs") to learn about introductory kinetics. Students created their own bath bombs by combining…

The redox reaction between dioxovanadium(V) and oxalate is proposed as a suitable system to analyze the kinetics of a twostep reaction mechanism using UV-vis spectroscopy. First, the spectra of dioxovanadium(V) and its reduced counterpart oxovanadium(IV) are compared and explained using the crystal field theory. The change in absorbance can be…

Here we present a new undergraduate laboratory that will introduce the concepts of time-resolved spectroscopy and provide insight into the natural time scales on which chemical dynamics occur through direct measurement. A quantitative treatment of the acquired data will provide a deeper understanding of the role of quantum mechanics and various…

A laboratory experiment that exposes students to fundamental concepts in kinetics and statistical thermodynamics to study systems of great current interest in nanotechnology by employing a foundational technique in physical chemistry is described. A modified commercial flash photolysis spectrometer was used to study photoinduced isomerization…

The effects of kinetic vs thermodynamic control on "endo"/"exo" stereoisomer ratios can be observed in a simple Diels-Alder reaction between "N"-phenylmaleimide and furan. The use of microwave-promoted synthesis affords the cycloadducts in yields ranging from 65-100%, employing reaction times of 1-10 min at…

What if "every breath you take, every move you make" (Sting 1983) could be harnessed to produce renewable energy? Triboelectric nanogenerators (TENGs) are state-of-the-art devices researchers are studying to do just that--convert kinetic energy into electrical energy at the source (Saurabh Rathore 2018). This type of electrical energy is…

As the need for alternative energy becomes increasingly important, energy research and related industries are rapidly expanding. This lab incorporates current energy-storage research into a second-year lab that instills real-world, industry-relevant knowledge and skills while teaching and reinforcing physical-chemistry concepts. A manganese oxide…

An experimental protocol that provides an excellent way to discuss concepts at the crossroads of organic chemistry and biochemistry employing biocatalysis is presented. By evaluating several reaction parameters (enzyme source, organic solvent, and acyl donor), it was possible to conduct an enzymatic kinetic resolution experiment using…

The law of conservation of momentum can be applied to a wide range of processes whether it is the collision of subatomic particles, rocket propulsion, or the recoil of a cannon. In this experiment two technologies, the Arduino microcontroller and a PASCO smart cart, are used to create a movable rubber band launcher. The Arduino microcontroller is…

Artificial photosynthesis (AP) is a synthetic chemical process that replicates natural photosynthesis to mass produce hydrogen as a clean fuel from sunlight-driven water splitting (2H[subscript 2]O [right arrow] O[subscript 2] + H[subscript 2]). In both natural and artificial photosynthesis, an oxygen-evolving catalyst (OEC) is needed to catalyze…

Students in the undergraduate "transport phenomena" courses typically have a greater difficulty in understanding the theoretical concepts underlying the mass transport phenomena as compared to the concepts of momentum and energy transport. An experiment based on dissolution of carbon dioxide in water was added to the course syllabus to…