The current study examined associations of intersectional social identities on Black women's (N = 126) career self-efficacy and interests at a Historically Black College and University (HBCU). Structural models examined associations of different aspects of gender and racial identity on Social Cognitive Career Theory (SCCT) predictors (i.e., learning experiences and self-efficacy) for each RIASEC career interest. Social Cognitive Career Theory paths from learning experiences to career interests, via self-efficacy, were supported for all six career interests. For gender norms, domesticity directly predicted learning experiences and indirectly predicted interests for enterprising, investigative, social, and conventional themes; however, primacy of work conformity was not associated with learning experiences or indirect effects for any career interest. Racial centrality only predicted learning experiences and indirect effects on career interests for social careers. Aspects of racial and gender identity may set forth educational decisions that have implications for the eventual careers that many undergraduates pursue.