Academically gifted students or high potential learners don't feel challenged in regular classrooms. Teachers in schools are also not quipped with pedagogical interventions to meet the advanced learning needs of gifted students. Mentoring is considered an effective method to guide, motivate and optimize learning abilities of gifted students. The present paper discusses the process of developing a mentoring program for 32 gifted students in Science and Math who were selected through a two-tier identification process. Students were selected from three different locations in India and were invited to attend residential mentoring program in University of Delhi, Delhi. Students were administered Wechsler Intelligence Test (WISC) IV, Test of Intelligence and were closely observed during the mentoring session. Statistic analysis of WISC IV composite score and composite observation score indicated high positive correlation between the two scores and 93.75% students scored in top three categories of intelligence as specified in WISC IV score interpretation norm. Detailed qualitative analysis also helped to develop both learning profiles and a specific mentoring program for individual students.