Green chemistry metrics and life-cycle analysis (LCA) were used to assess inefficiencies in two current organic chemistry experiments conducted in third-year organic chemistry to synthesize ("E")-stilbene from benzaldehyde. An alternative Wittig-based, greener, one-pot experiment using the same starting material was selected as a vehicle…

At many universities, silver nitrate is used in teaching laboratories, and a resulting waste product is often silver chloride. Silver chloride is not a compound that can be discarded into a sink as it has harmful effects to the environment; however, commercial waste disposal is costly, and replacement of the silver nitrate reagent is expensive.…

College and university science programs generate hazardous waste that must be dealt with and disposed of in accordance with state and federal regulations. During a recent renovation and addition project for the State University of New York at Plattsburgh (SUNY Plattsburg), the author was contracted to analyze existing regulations, research best…

This project involved developing a method to remediate large quantities of aqueous waste from a general chemistry laboratory experiment. Aqueous Ni(II) waste from a general chemistry laboratory experiment was converted into solid nickel hydroxide hydrate with a substantial decrease in waste volume. The remediation method was developed for a…

Presents a sample contract for disposing of hazardous wastes in an environmentally sound, timely manner in accordance with all federal, state, and local requirements. Addresses situations where hazardous waste must be disposed of outside the laboratory and where alternate disposal methods are not feasible. (JN)

Procedures for recovering silver and cobalt from laboratory wastes (including those resulting from student experiments) are presented. The procedures are generally applicable since only common, inexpensive laboratory reagents are needed. (JN)

Topics and issues related to toxic wastes in academic laboratories are addressed, pointing out that colleges/universities are making efforts to dispose of hazardous wastes safely to comply with tougher federal regulations. University sites on the Environmental Protection Agency Superfund National Priorities List, costs, and use of lab packs are…

This article presents the results of a study to identify problems and recommend solutions to training and education deficiencies of the environmental workforce for risk assessment and hazardous waste. Cites five recommendations developed as a result of a workshop held in March 1986. (Author/CW)

Describes procedures for disposing of dichromate cleaning solution, picric acid, organic azides, oxalic acid, chemical spills, and hydroperoxides in ethers and alkenes. These methods have been tested under laboratory conditions and are specific for individual chemicals rather than for groups of chemicals. (JN)

Chromium(VI) compounds are classified as oxidizers and must be specially packaged and transported for disposal while Cr(III) compounds are considered nonoxidizers. A process which reduces Cr(VI) to Cr(III) by adding sodium metabisulfite followed by neutralization with magnesium hydroxide is explored. (MVL)

Describes simple, efficient techniques for treating hazardous chemicals so that nontoxic and nonhazardous residues are formed. Discusses general rules for management of waste chemicals from school laboratories and general techniques for the disposal of waste or surplus chemicals. Lists specific disposal reactions. (CW)

An objective of the American Chemical Society is to promote alternatives to landfilling for the disposal of laboratory chemical wastes. One method is to reduce the amount of chemicals that become wastes. This is the basis for the "less is better" philosophy. This bulletin discusses various techniques involved in purchasing control,…

Discusses the need for determining a curriculum to provide qualified hazardous waste personnel. Describes the needed role of colleges and universities and current hazardous materials certification requirements. Lists requirements for 18 professional certifications. (MVL)

Estimates that about 30,000 universities, colleges, and high schools produce a total of 4000 metric tons of hazardous waste annually. Discusses the difficulties that academic institutions have in disposing of small amounts of waste. Lists college courses with the potentially hazardous wastes usually produced. (MVL)

Presents relevant statistics accumulated in a fall organic laboratory course. Discusses laboratory equipment setup to lower the amount of waste. Notes decreased solid wastes were produced compared to the previous semester. (MVL)