As simple and ubiquitous redox-active organic molecules, quinones participate in diverse electron transfer processes in chemistry and biological systems for energy transformation and signal transduction. We introduce here a practical exercise to study the redox potentials of benzoquinone and its two derivatives by combining the electrochemistry…

The Arduino microcontroller is currently one of the favorite tools of makers, and many teachers have used it in teaching or experiments. In addition, light-emitting diode (LED) smart lighting is the worldwide trend in lighting. There are many teaching demonstrations or applications of color addition using LEDs. Furthermore, the Internet of Things…

Single slit diffraction and the thermal expansion of materials are common components of an undergraduate physics course, though these topics are often taught independently in both lectures and laboratory based courses. Higher levels of cognitive domains can be achieved by building on these established topics and combining them into a single…

As part of their third-year general chemistry program, students at the University of the Côte d'Azur are taught the basics of radioactivity. The view that third-year university students have of the periodic Table of the Elements is often reduced because it ignores the vast majority of isotopes. As part of this program, a practicum devoted to the…

We present a thermodynamics experiment suitable for first year undergraduate students employing Stirling Engines to create a demonstration of energy transformation and to measure the mechanical efficiency of such engines. Using an inexpensive transparent chambered Stirling Engine, students can connect concepts such as the theoretical…

Millions of people do not have access to clean drinking water; thus, cost-efficient water treatment systems are vital. Chemists, environmentalists, technicians, and engineers will be the professionals making breakthroughs in this industry. This laboratory experiment aims to introduce undergraduate students to the removal of pollutants from water…

Keto-enol tautomerism is a fundamental concept that examines the migration of a proton between two constitutional isomers, the keto and enol tautomer. Many experiments have been proposed to understand the concept behind Meyer's Rule, which states that the keto tautomer is favored as the solvent polarity increases. However, all the experiments have…

The effects of kinetic vs thermodynamic control on "endo"/"exo" stereoisomer ratios can be observed in a simple Diels-Alder reaction between "N"-phenylmaleimide and furan. The use of microwave-promoted synthesis affords the cycloadducts in yields ranging from 65-100%, employing reaction times of 1-10 min at…

This paper provides seven topics on sodium hydrogen carbonate (NaHCO[subscript 3]) and its ions for readers looking for familiar material phenomena to strengthen students' understanding of the chemical concepts of thermodynamics. The first concept is the ideal gas law, followed by the van't Hoff equation, Gibbs energy, pH change, chemical…

This study has proposed a simple method to show the convective heat transfer. The object in this study is an air conditioner (AC) as a simple case of convection. In addition, AC is also easy to find in the class because most classrooms in Indonesia installed AC. Usually, a visualization needs special software (i.e. MatLab or others) and good…

This thesis contains two areas of research. The first part contributes to the field of engineering mechanics. This research investigates the thermomechanical shape memory behavior of shape memory alloy (SMA) springs. As SMA springs undergo stress- and/or temperature-induced phase transformation, they experience varying combinations of axial,…

Thermodynamic characterization of micelle formation from an ionic surfactant in aqueous solutions is a classic experiment in physical chemistry. The critical micelle concentration (CMC) and the degree of micelle ionization ([alpha)] can be directly obtained by conductimetry, then thermodynamic parameters ([delta]G[subscript m][superscript o],…

The Hofmeister series is a recurring trend that ranks ions' abilities to influence various aqueous processes in solution. Herein, a set of project-based experiments was developed for students in an upper-level physical chemistry laboratory to investigate the specific ion effects on the thermodynamics of caffeine partitioning between aqueous and…

The ability to visualize chemical processes can be an asset in a teaching laboratory. Despite the advances in laboratory technology, apparatuses used in the teaching of simple thermodynamics concepts, such as exothermic/endothermic reactions, historically remain unchanged and can benefit from a fresh perspective. The recent incorporation of…

Synthesis and characterization of nanomaterials yields opportunities for instruction of related topics in solution chemistry and materials science, as well as spectroscopy connecting to band theory, the "particle in a box" quantum mechanical model, and thermodynamics. In collaboration with an undergraduate research assistant, we have…