The ideal gas law, "PV = nRT," is one of the simplest physical laws in nature that is introduced to students as early as in high school and first year in college. In this equation, "P" stands for pressure, "V" is the volume, "n" is the amount expressed in mole, "T" is the temperature in Kelvin…

The concept of an atom with an expanded octet, known as hypervalency, has persisted in the general chemistry curriculum, despite abundant theoretical work disputing its veracity. Here, the electronic structure of traditionally hypervalent molecules (H[subscript 2]SO[subscript 3], H[subscript 2]SO[subscript 4], PF[subscript 5], and SF[subscript 6])…

Students in one discipline often receive their scientific training from faculty in other disciplines. As a result of tacit disciplinary differences, especially as implemented in courses at the introductory college level, such students can have difficulty in understanding the nature of the knowledge they are learning in a discipline that they do…

Promoting students' ability to engage in discipline-specific practices is a central goal of chemistry education. Yet if instruction is to meaningfully foster such ability, we must first understand students' reasoning during these practices. By characterizing constraints on chemistry students' reasoning, we can design instruction that targets this…

Reaction coordinate diagrams (RCDs) are chemical representations widely employed to visualize the thermodynamic and kinetic parameters associated with reactions. Previous research has demonstrated a host of misconceptions students adopt when interpreting the perceived information encoded in RCDs. This qualitative research study explores how…

The central goal of this exploratory study was to characterize the effects of experiments involving different levels of inquiry on the nature of college students' written reflections about laboratory work. Data were collected in the form of individual lab reports written using a science writing heuristic template by a subset of the students…

We have applied the heuristic-analytic theory of reasoning to interpret inconsistencies in student reasoning approaches to physics problems. This study was motivated by an emerging body of evidence that suggests that student conceptual and reasoning competence demonstrated on one task often fails to be exhibited on another. Indeed, even after…

Diverse implicit cognitive elements seem to support but also constrain reasoning in different domains. Many of these cognitive constraints can be thought of as either implicit assumptions about the nature of things or reasoning heuristics for decision-making. In this study we applied this framework to investigate college students' understanding of…

The Domenico solution is a heuristic simplification of a solution to the transport equation. Although there is a growing consensus that the Domenico solution is undesirable for use in professional and research applications due to departures from exact solutions under certain conditions, it behaves well under conditions suitable for instruction.…

The mental models of both novice and advanced chemistry students were observed while the students performed a periodic table activity. The mental model framework seems to be an effective way of analyzing student behavior during learning activities. The analysis suggests that students do not recognize periodic trends through the examination of…

The connection between the molecular-level structure of a substance and its macroscopic properties is a fundamental concept in chemistry. Students in college-level general and organic chemistry courses were interviewed to investigate how they used structure-property relationships to predict properties such as melting and boiling points. Although…

This study examined the representational competence of students as they solved problems dealing with the temperature-pressure relationship for ideal gases. Seven students enrolled in a first-semester general chemistry course and two advanced undergraduate science majors participated in the study. The written work and transcripts from videotaped…

Although the presentation of quantum mechanics found in traditional textbooks is intellectually well founded, it suffers from a number of deficiencies. Specifically introducing quantum mechanics as a solution to the arcane dilemma, the ultraviolet catastrophe, does little to impress a nonscientific audience of the tremendous paradigmatic shift…

This study aims to add to the growing research related to the implementation of non-traditional writing tasks in classrooms to encourage science literacy. A secondary reanalysis methodology was employed to review student interviews collected as a part of several individual studies during a ten year research program. This method established an…

We investigate the efficiency of domain-specific heuristic strategies in mastering and predicting pericyclic six-electron rearrangements. Based on recent research findings on these types of reactions a new concept has been developed that should help students identify and describe six-electron rearrangements more readily in complex molecules. The…