Physics experts and students commonly use a variety of representations when working with partial derivatives, including symbols, graphs, and words. One especially powerful representation is the contour graph. In open-ended problem-solving interviews with nine upper-division physics students, we asked students to determine derivatives from contour…

Spontaneity criteria for processes with useful (especially electrical) work have been discussed based on total differentials of thermodynamic functions. Reaction Gibbs energy ([Delta][subscript r]G) and electrochemical reaction Gibbs energy ([Delta][subscript r]G~) have been juxtaposed. Three-dimensional graphs showing the dependencies of…

Chemical equilibrium is one of the most important concepts in chemistry. The changes in properties of the chemical system at equilibrium induced by variations in pressure, volume, temperature, and concentration are always included in classroom teaching and discussions. This work introduces a novel, geometrical approach to understanding the…

The elementary reaction sequence A ? I ? Products is the simplest mechanism for which the steady-state and quasi-equilibrium kinetic approximations can be applied. The exact integrated solutions for this chemical system allow inferring the conditions that must fulfill the rate constants for the different approximations to hold. A graphical…

This paper presents a comparative study of the thermal efficiencies of mechanical heat engines by using a graphical approach based on the pressure-volume ("P-V") diagram. Three types of idealized thermodynamic cycles--the Otto, the Diesel and the Brayton--are compared in pairs. Given the same temperature range within which the engines…

During the years 1873-1879, J. Willard Gibbs published his now-famous set of articles that form the basis of the current perspective on chemical thermodynamics. The second article of this series, "A Method of Geometrical Representation of the Thermodynamic Properties of Substances by Means of Surfaces," published in 1873, is particularly notable…

The use of qualitative graphs of Gibbs energy versus temperature is described in the context of chemical demonstrations involving phase changes and colligative properties at the general chemistry level. (Contains 5 figures and 1 note.)

Outlines a teaching method using graphs for explaining phase changes and the effect of pressure and the relationships between temperature, entropy, enthalpy, energy, Gibbs function, Helmholtz function and volume. (GS)

Discusses the concepts involved in constructing a meaningful free energy plot for a chemical reaction and how these concepts are sometimes insufficiently represented in textbooks. (MLH)

Described is a computer software package suitable for teaching and research in the area of multicomponent vapor-liquid equilibrium. This program, which has a complete database, can accomplish phase-equilibrium calculations using various models and graph the results. (KR)

This publication is a laboratory study guide designed for mechanical engineering students. All of the experiments (with the exception of experiment No. 1) contained in the Mechanical Engineering Laboratory Manual have been included in this guide. Brief theoretical backgrounds, examples and their solutions, charts, graphs, illustrations, and…