A problem-based learning (PBL) methodology was implemented to a project, whose main objectives were to discuss and apply the Twelve Principles of Green Chemistry to the study of poly(vinyl alcohol)'s cross-linking reaction with dicarboxylic acids. The five participating students were oriented to be responsible for their own learning and the…

Selecting less hazardous chemicals is a core tenet of green chemistry but is difficult to teach in practice. The upper-year undergraduate or graduate level exercise described here empowers students to make such decisions themselves. Students are tasked with finding the greenest chemical for a specific purpose described in a hypothetical scenario,…

The ability to handle chemicals safely is a key aspect of the learning development of students studying chemistry; however, there have been no previously reported investigations of the quantity of chemicals spilled by students during lab experiments. Therefore, the first part of this article reports the assessment of the volume of chemicals…

College laboratories are generally perceived to be low-risk environments in comparison to industrial laboratories and plant operations. However, accidents in college chemistry laboratories have revealed the safety conditions to which both students and staff may be exposed. Improving the effectiveness of laboratory safety training programs and…

Rovibrational spectroscopy is a fundamental component of most physical chemistry curricula. This article describes an adaption of the rovibrational spectroscopy of carbon dioxide experiment that can be used as a stand-alone experiment or in conjunction with a traditional hydrogen chloride experiment. The case is made that the laboratory…

A systems thinking approach to incorporating green chemistry and safety into laboratory culture is vital, as chemists will be at the molecular level of the innovative solutions to our global challenges. Training chemists to have the skills and culture to accomplish this feat in the safest way possible is pivotal to safe working conditions within…

Polychlorinated biphenyls (PCBs) are a family of synthetic chemicals consisting of carbon, hydrogen, and chlorine atoms. PCBs have been produced commercially since 1929 in hundreds of industrial applications. Their continued production in the United States was phased out in the late 1970s, and strict disposal guidelines were regulated as adverse…

This study aims at investigating students' awareness of green chemistry principles (GCPs) which are infused in two context-based projects that are related to socio-scientific issues, namely climate change and materials' recycling. At first, content analysis of the projects' activities showed the infusion of four GCPs. Subsequently, the students'…

The most important indicator of meaningful learning in science education is that the students learn and often encounter in their daily life in the description. To be able to implement this, students need to be a good science literate. This study was carried out in order to reveal to what extent the teacher candidates can explain the relationship…

This paper describes a method for determination of trihalomethanes (THMs) in drinking water via solid-phase microextraction (SPME) GC/MS as a means to develop and improve student understanding of the use of GC/MS for qualitative and quantitative analysis. In the classroom, students are introduced to SPME, GC/MS instrumentation, and the use of MS…

Due to the unique and advantageous physiochemical properties of nanoparticles, they have been increasingly incorporated into consumer products and emerging technologies. The manufacture, wear and tear of use, and disposal of these nano-enabled products will likely result in the release of nanoparticles into the environment. Unfortunately,…

Exothermic reactions can present safety hazards and there is a recognized need for reaction safety education at the undergraduate level. We present an experiment that illustrates the pitfall of direct scale-up of an exothermic reaction that can lead to thermal runaway. The iodide-catalyzed hydrogen peroxide decomposition reaction yields…

The university traditionally has been the foundation for young adults' professional development, yet the proclivity toward safety culture has garnered less focus in higher education than in the workforce. A survey of faculty at a medium-sized, research-active, private institution revealed specific areas of policy noncompliance as well as specific…

We demonstrate here a novel laboratory experiment for the synthesis of gold nanoparticles (AuNPs) by using a low energy gold-sputtering method together with a modern, green, and biofriendly deep eutectic solvent (DES). The strategy is straightforward, economical, ecofriendly, rapid, and clean. It yields uniform AuNPs of 5 nm in diameter with high…

A summer workshop was offered to inner-city high school students to explore the sustainability of their consumer choices using a systems thinking model. Students learned about related environmental or health issues due to the manufacturing, use, or disposal of common household products. Then, in the laboratory, they performed experiments to…