Despite extensive conceptualization of ions as hard spheres in most textbooks, solid-state structures are more accurately modeled as overlapping soft spheres that better reflect the size of the ions. The corresponding soft-sphere ionic radii of alkali and halide ions can be empirically established from the partial molar volume of the ions in…

Laboratory activities are a prevalent and essential part of chemistry learning because of their potential to help students develop problem solving abilities, visualize chemistry concepts learned in lecture, and gain practical skills. However, learning in the laboratory environment is not without its challenges. For example, cookbook-style…

A national survey on chemistry instructional laboratories was administered to faculty members at four-year postsecondary institutions in the United States for the purpose of exploring levels of inquiry-based instruction implemented in laboratory courses. Respondents were asked to rate the level of choice their students had in deciding six key…

This experiment provides students with a thorough understanding of electrolysis and the parameters that most greatly impact optimization of this process. In this laboratory exercise, students will focus on the anodization of bismuth metal to develop thin oxide films. When designing an electrolytic cell devoted to anodization, there are several…

With the advancements in broad-spectrum sunscreens and the recent bans on benzene-based sunscreens due to their environmental toxicity, there has been a push toward broad-spectrum sunscreens containing in organic active ingredients. In this study, a procedure was developed to analyze the particle size and size distribution of inorganic active…

A physical organic chemistry experiment is described for second-year college students. Students performed nucleophilic aromatic substitution (NAS) reactions on 5,10,15,20-tetrakis(2,3,4,5,6-pentafluorophenyl)porphyrin (TPPF[subscript 20]) using three different nucleophiles. Substitution occurs preferentially at the 4-position ("para")…

Although demonstrations play a central role in teaching and learning chemistry, the effects of concrete setup principles have rarely been subject to systematic empirical studies. According to the left-to-right principle, the educator should begin with the first step of a reaction in the upper left part of the setup and then place the following…

The so-called Diet Coke and Mentos experiment is initiated by dropping Mentos candies into a bottle of Diet Coke or other carbonated beverage. This causes the beverage to rapidly degas, causing foam to stream out of the bottle. Simple application of the gas laws leads to the straightforward prediction that ejection of greater foam volume is…

A new undergraduate inorganic chemistry laboratory experiment is presented. An introduction of the spectrochemical series and ligand exchange is explored using the coordination complex dirhodium tetraacetate, Rh[subscript 2](OAc)[subscript 4]. Students have measured the absorption spectra of the Rh[subscript 2] complex in the presence of various…

General chemistry students need to understand the concept of intermolecular forces and use them to predict the properties of materials. To do this, they must create symbolic representations of molecules, relate these to physical observations, and explain them using submicroscopic theoretical constructs. When these concepts are taught separately,…

This paper seeks to investigate how students' performance in Chemistry can be enhanced by using kitchen resources in Calabar. The kitchen resources used included a piece of white paper, a swab, lemon juice and candle. These were used to show that paper cellulose was oxidized by flame due to the catalysis of lemon juice acid. Other materials used…

Persistence is a major issue facing students, particularly those who are both female and from underrepresented ethnic minorities (URM). A closer look at the variables affecting their commitment and capacity for continuing the pursuit of their goal allows us to better design support systems that bolster persistence. This study tests a structural…

The science laboratory learning environment has been a distinctive area in science education since the 19th century. Unfortunately, students are generally not aware of what science instructors expect from laboratory experiences, and far too often, the undergraduate science laboratory curriculum lacks explicit, well-defined goals. Science…

In selecting from a repertoire of traditional kinetics experiments, an instructor often has to choose among having students gain experience with the graphical method, the method of initial rates, or a temperature-dependent experiment in which students construct an Arrhenius plot. This paper presents an environmentally friendly bleaching reaction…

As a fundamental part of their chemical education, first-year undergraduate students are substantially involved in laboratory activities. Despite the specific teaching staff choices on the main laboratory aims, students normally receive a vast amount of information during these activities. Apart from understanding theoretical content, fundamental…