Anaerobic respiration reactions are of fundamental importance to global biogeochemical cycling of elements. Yet, the idea that cellular respiration can occur not only in the absence of oxygen but also involve the oxidation of inorganic substrates (e.g., AsO[subscript 3 superscript 3-], Fe[superscript 2+], H[subscript 2], H[subscript 2]S,…

As simple and ubiquitous redox-active organic molecules, quinones participate in diverse electron transfer processes in chemistry and biological systems for energy transformation and signal transduction. We introduce here a practical exercise to study the redox potentials of benzoquinone and its two derivatives by combining the electrochemistry…

This study adds to the growing body of research on laboratory work. The study involves four pairs of students in a university introductory calorimetry lab of which two pairs, the IR-pairs (infrared camerapairs), were given access to infrared cameras to use however they liked during their course lab work. Two other pairs, the T-pairs…

The fundamental principles and applications of thermodynamics and single-component phase equilibrium are used to explain and quantitatively analyze the operation and performance of the vapor-compression refrigerator (VCR). Carbon dioxide is used as the refrigerant. The four processes (or steps) that comprise the VCR refrigeration cycle are…

Fundamentals of Macroscopic Chemical Analysis is a newly developed foundation-level course that integrates concepts from traditional physical and analytical chemistry courses. The course was designed to serve majors in chemistry, biochemistry, and biology as well as pre-health professional students. The main goal of this course is to develop the…

As part of their third-year general chemistry program, students at the University of the Côte d'Azur are taught the basics of radioactivity. The view that third-year university students have of the periodic Table of the Elements is often reduced because it ignores the vast majority of isotopes. As part of this program, a practicum devoted to the…

Redox reactions and their balancing are one of the basic chemistry subjects in which students may experience remarkable learning difficulties at the beginning of their university career. This topic represents an evolution of stoichiometry concepts related to the balancing of chemical reactions and can be taught with different approaches as a…

This paper seeks to evaluate learning based on the competency approach, taking a didactic experience to evaluate a possible improvement in the ability to solve problems and for autonomous learning in general. For the didactic development, the theme "gases" was taken, which is generally enunciated: Corpuscular kinetic theory of matter;…

Millions of people do not have access to clean drinking water; thus, cost-efficient water treatment systems are vital. Chemists, environmentalists, technicians, and engineers will be the professionals making breakthroughs in this industry. This laboratory experiment aims to introduce undergraduate students to the removal of pollutants from water…

The design and operation of the vapor-absorption refrigerator (VAR) are described using the principles and tools typically covered in upper-division undergraduate physical chemistry courses. The objective is to enable students to understand in detail how this device works and how it compares with more typical vapor-compression refrigerators.…

Keto-enol tautomerism is a fundamental concept that examines the migration of a proton between two constitutional isomers, the keto and enol tautomer. Many experiments have been proposed to understand the concept behind Meyer's Rule, which states that the keto tautomer is favored as the solvent polarity increases. However, all the experiments have…

A laboratory experiment that exposes students to fundamental concepts in kinetics and statistical thermodynamics to study systems of great current interest in nanotechnology by employing a foundational technique in physical chemistry is described. A modified commercial flash photolysis spectrometer was used to study photoinduced isomerization…

Seeking to foster the learning process and encourage the active participation of undergraduate students, this work proposes a new methodology that involves integrating smartphones into the learning process under a simple and accessible approach to learning in Chemistry and Physics laboratories aiming at facilitating the learning of some chemical…

The effects of kinetic vs thermodynamic control on "endo"/"exo" stereoisomer ratios can be observed in a simple Diels-Alder reaction between "N"-phenylmaleimide and furan. The use of microwave-promoted synthesis affords the cycloadducts in yields ranging from 65-100%, employing reaction times of 1-10 min at…

For 26 years, it has been assumed by some that the thermodynamics of open-system biochemical reactions must be executed by performing Legendre transformations on the terms involving the species whose concentrations are being held fixed. In contrast, standard nontransformed thermodynamics applies to chemical processes. However, it has recently been…