Modifications are presented for the iodine clock reaction to introduce the concept of activity and to help students better appreciate molecular aspects of chemical equilibrium. The addition of an unreactive salt affects the activity of the reactants in the iodine clock reaction. The difference in activity affects how long the iodine clock reaction…

A laboratory experiment has been designed for teaching laboratories aimed at training students in the basics of spectroscopy in junior and senior level undergraduate chemistry courses. Despite the ubiquity of light-based tools in modern science, students often find it difficult to comprehend light and light-matter interactions. A portable…

An activity of using waste plastic caps and wooden sticks (or steel wires) to construct crystal structures is described. Caps with different colors represent different atoms/ions/interstices, and sticks are employed to carry the caps and describe the positions of atoms/ions/interstices. The cap-and-stick model clearly demonstrates crystal…

The area of application of electrospray ionization mass spectrometry (ESI-MS), usually coupled with liquid chromatography, seems to be much larger than those of any other ionization method. It gives rise to the demand for new teaching methods that would effectively help students to master the principles of working with and making full use of the…

A convenient approach to obtain Lewis structures for compounds of the type YX[subscript n] involves first constructing a trial structure that satisfies the valence of the outer atoms (e.g.,1 bond for fluorine, 2 bonds for oxygen, and 3 bonds for nitrogen)and placing the molecular charge (if any) on the central atom. The second step involves…

A chemistry laboratory experiment is described to introduce undergraduate college students to membrane separation technology. This experiment combines a simple nanowire membrane fabrication and visually indicated molecule separation. The membrane is produced via coprecipitation synthesis followed by a filtration assembly process, which can be…

As a widely applied theory that has found success across many fields, density functional theory (DFT) is largely taught. Typically, the most effective way to convey DFT concepts is through illustrative examples that are currently lacking in available resources. In this work, we demonstrate total energy calculations for H[subscript 2] using…

Valence shell electron pair repulsion theory (VSEPR) as explained in most textbooks predicts that substituents bonded to a central atom in AX[subscript n]E[subscript z][superscript c] species (A = main-group central atom, X = substituent, E = lone pair on central atom, c = charge) will change their X-A-X angles to bend away from the lone pairs.…

Auxiliary Tanabe-Sugano diagrams are presented. They enable a rapid and reliable graphical derivation of Dq/B and C/B crystal field parameter ratios from spectroscopic data. Using these values, one can calculate Dq and B by employing the original Tanabe-Sugano diagrams. Subsequently, C can also be calculated irrespective of the value C/B fixed in…

A new teaching resource comprised of raw X-ray diffraction data sets from crystallography experiments has been compiled. The aim of this resource is to provide a tool with which to plug the teaching gap between crystals and chemical structures present at various levels of education, as well as providing examples for early stage researchers and…

Approximations can help to orient the student in an organic chemistry laboratory. There the student needs to develop the solvent systems for the reaction and isolation of organic reactants and products. The adage "like dissolves like" helps in this regard, but this approach is vague and entirely qualitative. More quantitative approaches…

Climate change is a critical scientific and social issue of our time, yet the topic is not frequently discussed by the general public. Additionally, misconceptions about the topic persist. One important aspect of climate change is the greenhouse effect. This activity adds a greenhouse gas discussion to an existing module about molecular shape and…

Biochemistry students at the introductory level easily comprehend the importance of energy-yielding oxidation and reduction biochemical processes, but nevertheless, they fight with words "oxidation" and "reduction" (and with the corresponding adjectives, "oxidized" and "reduced") applied in biochemistry…

When structure-property relationships are discussed in inorganic chemistry and materials science, the common perception is that materials with the same composition and atomic arrangement have the same properties. In this laboratory experiment, we show that "processing"--the exact conditions under which materials are made--can in fact…

Organic molecules are invisible objects, but they can be visualized and manipulated by using molecular models. The object-based learning (OBL) approach, which is an educational tool developed for museums and collection items, is tailored and applied to a first-year bachelor course of organic chemistry. At the beginning of the course, each student…