For most chemistry curricula, laboratory-based activities in quantitative and instrumental analysis continue to be an important aspect of student development/training, one that can be more effective if conceptual understanding is delivered through an inquiry-based process relating the material to relevant issues of public interest and student…

Students' attitudes toward and conceptual understanding of chemical instrumentation is surveyed. The study shows that, in general, the students' attitudes toward using instrumentation in the lab is quite positive and they felt that using instrumentation in the lab allowed them not only to connect "chemistry" and the "real world", but also to…

Described is an experiment to investigate the plasticizer content in polyvinyl chloride (PVC) products. The experiment is designed for college students using an instrumental analysis laboratory. (RH)

A description is given of work undertaken to develop a simple, specific, and reliable method for ozone. Reactions of ozone with several 1-alkenes were studied at room temperature (25C). Eugenol (4-allyl-2-methoxy phenol), when reacted with ozone, was found to produce relatively large amounts of formaldehyde as compared to other 1-alkenes tested.…

Total mercury in ambient air can be collected in iodine monochloride, but the subsequent analysis is relatively complex and tedious, and contamination from reagents and containers is a problem. A sliver wool collector, preceded by a catalytic pyrolysis furnace, gives good recovery of mercury and simplifies the analytical step. An instrumental…

Following a delineation of thermoluminescence from a historical perspective and a qualitative description of the process, a treatment of the kinetic process based on a simple model is presented. This treatment model is adequate for the purpose of identifying the essential requirements in instrument design. (BT)

A questionnaire was mailed to 50 major chemistry departments, 112 smaller chemistry departments, and 25 chemical engineering (CE) departments. The survey (included in an appendix) consists of a series of questions on two broad subjects--the current inventory at the surveyed institutions and the needs for instrumentation. Responses were received…

Using fourier transformation methods in nuclear magnetic resonance has made possible increased sensitivity in chemical analysis. This article describes these methods as they relate to magnetization, the RF magnetic field, nuclear relaxation, the RF pulse, and free induction decay. (CW)

Addresses solution nonmetal determinations on a fundamental level. Characterizes research in this area of chemical instrumentation. Discusses the fundamental limitations of nonmetal atomic spectrometry, the status of nonmetals and atomic spectroscopic techniques, and current directions in solution nonmetal determinations. (CW)

The National Survey of Academic Research Instruments and Instrumentation Needs is a congressionally mandated program that collects data concerning scientific research instruments and the academic departments and facilities in which they are located. This report analyzes overall instrumentation issues and trends in all the fields covered by the…

The current manual NO (x) sampling and analysis method was evaluated. Improved time-integrated sampling and rapid analysis methods were developed. In the new method, the sample gas is drawn through a heated bed of uniquely active, crystalline, Pb02 where NO (x) is quantitatively absorbed. Nitrate ion is later extracted with water and the…

A prototype model low level carbon monoxide analyzer was developed using fluorescent cell and negative chopping techniques to achieve a device superior to state of art NDIR (Nondispersive infrared) analyzers in stability and cross-sensitivity to other gaseous species. It is clear that this type of analyzer has that capacity. The prototype…

Explores neurochemical events in the extra cellular space of the brain by use of in vivo voltammetric microelectrodes. Reports dopamine concentrations and pathways, and discusses techniques used for analysis. Recognizes current problems and future directions for research. (ML)

Discusses three aspects of electrochemical detectors: (1) signal and noise generation and signal-to-noise ratio, (2) improvement of qualitative information content, and (3) control of selectivity of the detector. Explains electronic principles of detectors and detection limits. Lists current applications and research. (ML)

This report presents priorities for new facilities and new capabilities at existing facilities with initial costs of at least $5 million. The new facilities in order of priority are: (1) a 6 GeV synchrotron radiation facility; (2) an advanced steady state neutron facility; (3) a 1 to 2 GeV synchrotron radiation facility; and (4) a high intensity…