A facile synthesis of two gold(I) complexes with 1,2-benzenedithiolate ligand and two different bidentate phosphines are described. A detailed sequence of NMR experiments is suggested to determine the structure of the compounds.

Draws a distinction between the terms "heat and work" and "energy" in terms of the teaching of thermodynamics. Gives examples using enthalpy and constant pressure processes, free energy and spontaneity, and free energy and available mechanical energy. Concludes that there is no thermodynamic role for the terms "heat"…

It is suggested that molecular theory should be taught earlier in the inorganic chemistry curriculum even in the introductory chemistry course in order to integrate molecular orbital arguments more effectively throughout the curriculum. The method of teaching relies on having access to molecular modeling software as having access to such software…

Discusses the differences between iron and copper. Describes various aspects of the behaviors of these two elements, including those of biological and environmental significance. Addresses the evolution of the atmosphere and sedimentary ore formation, the phylogeny of iron and copper, and some anthropological notes regarding the use of the metals.…

Describes the potential health hazards of using thioacetamide in introductory courses where students are involved in qualitative inorganic analysis. Describes the chemical as possessing carcinogenic, hepatotoxic, and mutagenic properties. Cautions that thioacetamide has caused various biochemical changes in the liver, and recommends limited uses…

Surveys the outlook presented by former and present chemistry and biochemistry doctoral students toward their graduate program. Poses questions to determine what aspects are deemed important. Suggests seminars and quality advisors are important factors. (ML)

Argues that the field of inorganic chemistry is facing an identity crisis. Proposes that the current call for curriculum reform in inorganic chemistry is an opportunity to return to a stronger discipline. Presents a history of freshman chemical education and recommends a new program for inorganic chemistry. (TW)