The aim of this paper is to propose an original analysis of the association between social status and attitudes toward COVID-19 vaccines regarding upper-secondary students in Italy. The research was conducted by administering an online survey on a probabilistic and stratified sample of 5,699 students, in the spring of 2021, when the vaccination campaign in Italy had been underway for only a few months. Following the bourdieusian perspective, we have used a multiple correspondence analysis to examine the polarization between pro-vaccine and anti-vaccine groups as the clash of stances that agents take in accordance with their position in the cultural field. Our results suggest that the construction of a negative school experience by the subordinate classes is the source of a lack of social recognition in the cultural field, which feeds an aversion to everything the main institutions in this field recommend should be done.