An empirical investigation assessed the role of different factors of motivational, behavioral, and dispositional nature in the prediction of both perceived and actual skills concerning household waste recycling. A structured questionnaire (measuring attitudes, social norms, perceived control, need for cognitive closure, self-reported household recycling behavior and perceived recycling skills) and a simulation task (assessing actual recycling skills) were administered to 300 participants in Italy. Results indicate that, although positively related, perceived and actual skills are two distinct constructs differently related to motivational, behavioral, and dispositional factors. Implications for designing educational interventions to increase citizens' recycling skills are discussed.