A laboratory experiment in which [superscript 1]H NMR and UV-vis spectroscopies are applied to probe the temperature dependence of a monomer-dimer equilibrium involving a cyclopentadienone derivative is described and discussed. Details of the data analysis for extraction of equilibrium constants from the raw experimental data from both techniques…

Teaching upper division statistical physics can often be clouded by the theory and complex examples used. To better help students appreciate the fundamental statistical concepts and how they are connected to thermodynamic principles this paper suggests using a simple abstract model. Using Atkins' Model students can see these ideas clearly…

Background: Undergraduate students consistently struggle with mastering concepts related to thermodynamics. Prior work has shown that haptic technology and intensive hands-on workshops help improve learning outcomes relative to traditional lecture-based thermodynamics instruction. The current study takes a more feasible approach to improving…

Anaerobic respiration reactions are of fundamental importance to global biogeochemical cycling of elements. Yet, the idea that cellular respiration can occur not only in the absence of oxygen but also involve the oxidation of inorganic substrates (e.g., AsO[subscript 3 superscript 3-], Fe[superscript 2+], H[subscript 2], H[subscript 2]S,…

We describe the components and implementation of an activity for multivariable calculus featuring applications to the field of chemistry. This activity focuses on the isobaric thermal expansion coefficient found using partial differentiation of the volume of an ideal gas with respect to temperature as pressure is held constant. Broader goals of…

We use the Survey of Thermodynamic Processes and First and Second Laws-Long (STPFaSL-Long), a research-based survey instrument with 78 items at the level of introductory physics, to investigate introductory and advanced students' difficulties with entropy and the second law of thermodynamics. We present an analysis of data from 12 different…

Twenty nine students who had previously taken an undergraduate thermal physics course were interviewed about their basic knowledge about statistical mechanics at the undergraduate level. Of these 29, fourteen were undergraduate students, and fifteen were graduate students at varying stages of their career. This project aimed to identify and…

From literature, we know that making the connections between mathematics and physics is not trivial for most students, even at the advanced level. In the specific context of partial derivatives in thermodynamics, research suggests that making explicit connections between the mathematics and the physics is necessary to foster student understanding.…

We describe an experiment in which students use research-grade instrumentation to collect gas adsorption data in triplicate in a single 3 h laboratory period. The experiment reinforces the thermodynamic concepts taught in upper level physical chemistry courses and hands-on experience with instrumentation used in research laboratories. The speed of…

The inexorable rise in atmospheric carbon dioxide impacts not only global warming but also the acidity of the ocean. Increasing ocean acidity causes a decline in carbonate (as it is protonated), which in turn will negatively impact the ability of calcifying marine organisms to build their calcium carbonate shells. A simple set of equilibrium…

As simple and ubiquitous redox-active organic molecules, quinones participate in diverse electron transfer processes in chemistry and biological systems for energy transformation and signal transduction. We introduce here a practical exercise to study the redox potentials of benzoquinone and its two derivatives by combining the electrochemistry…

This study adds to the growing body of research on laboratory work. The study involves four pairs of students in a university introductory calorimetry lab of which two pairs, the IR-pairs (infrared camerapairs), were given access to infrared cameras to use however they liked during their course lab work. Two other pairs, the T-pairs…

The Arduino microcontroller is currently one of the favorite tools of makers, and many teachers have used it in teaching or experiments. In addition, light-emitting diode (LED) smart lighting is the worldwide trend in lighting. There are many teaching demonstrations or applications of color addition using LEDs. Furthermore, the Internet of Things…

We discuss the development and validation of the long version of a conceptual multiple-choice survey instrument called the Survey of Thermodynamic Processes and First and Second Laws-Long suitable for introductory physics courses. This version of the survey instrument is a longer version of the original shorter version developed and validated…

Understanding the physicochemical properties of organic compounds with potential biological uses is central in current research topics. Thus, students must pursue the integration of different fields of chemistry to obtain and understand the physicochemical parameters that characterize the mechanism of action of key organics compounds. This…