Analogies from life experiences help students understand various relationships presented in an introductory chemistry course. Coulomb's law is a complex relationship encountered in introductory general chemistry. A proper understanding of the relationships between the quantities involved in Coulomb's law is necessary in order for students to…

The three-step synthesis of Geodken's macrocycle, H[subscript 2]C[subscript 22]H[subscript 22]N[subscript 4], (5,14-dihydro-6,8,15,17-tetramethyldibenzo[b,i]-[1,4,8,11] tetraazacyclotetradecahexane), in an overall yield of 65% is described. By utilizing the synthesis of the macrocycle's dichloride salt, H[subscript 2]C[subscript 22]H[subscript…

The series of experiments proposed for advanced undergraduate students deal with both standard organometallic preparative methods in dry anaerobic conditions and with a kinetic study of the mechanisms operating in the substitution of square-planar complexes. The preparation of organometallic compounds is carried out by transmetallation or…

Before taking an inorganic laboratory course few students have experience handling air-sensitive materials using Schlenk techniques. This exercise introduces them to techniques they will employ in later syntheses. The procedure involves the formation of anhydrous tetrahydrofuran complexes of transition-metal chlorides from metal-chloride hydrates;…

A course module in general chemistry focusing on predicting the products of simple inorganic reactions is described. This component of the course is intended to be presented near the end of the last term of the general chemistry sequence and is designed to afford practice in applying the variety of principles encountered throughout the general…

A three-week laboratory project involving synthesis and characterization of a layered manganese oxide provides an excellent vehicle for teaching important concepts of inorganic chemistry and instrumental methods related to non-molecular systems. Na-birnessite is an easily prepared manganese oxide with a 7 A interlayer spacing and Na[superscript +]…

The kinetics experiments on the ligand-C[subscript 60] exchange reactions on (dihapto-[60]fullerene) pentacarbonyl tungsten(0), ([eta][superscript 2]-C[subscript 60])W(CO)[subscript 5], form an educational activity for the inorganic chemistry laboratory that promotes graphical thinking as well as the understanding of kinetics, mechanisms, and the…

This chemistry textbook presents a beginning course for schools or colleges. It presents a more complete classification than usual according to chemical analogies, the explanation of chemical phenomena in ordinary language, as well as symbols, and the addition of a complete set of formulae in the appendix. A number of recent and important…

This chemistry textbook presents a beginning course for schools or colleges. It presents a more complete classification than usual according to chemical analogies, the explanation of chemical phenomena in ordinary language, as well as symbols, and the addition of a complete set of formulae in the appendix. A number of recent and important…

This chemistry textbook presents a beginning course for schools or colleges. It presents a more complete classification than usual according to chemical analogies, the explanation of chemical phenomena in ordinary language, as well as symbols, and the addition of a complete set of formulae in the appendix. A number of recent and important…

This chemistry textbook presents a beginning course for schools or colleges. It presents a more complete classification than usual according to chemical analogies, the explanation of chemical phenomena in ordinary language, as well as symbolic language. A series of new and original designs are introduced, illustrating to the eye the groupings of…