The design and operation of the vapor-absorption refrigerator (VAR) are described using the principles and tools typically covered in upper-division undergraduate physical chemistry courses. The objective is to enable students to understand in detail how this device works and how it compares with more typical vapor-compression refrigerators.…

Keto-enol tautomerism is a fundamental concept that examines the migration of a proton between two constitutional isomers, the keto and enol tautomer. Many experiments have been proposed to understand the concept behind Meyer's Rule, which states that the keto tautomer is favored as the solvent polarity increases. However, all the experiments have…

Molecules and Computer: Chemistry Calculations in Class (MC[superscript 4]) is a computational laboratory intended for final-year high school or undergraduate students. The topic is the antioxidant potential of anthocyanidins, which is chemically related to their radical scavenging action via the mechanism of hydrogen atom transfer (HAT). This…

Recently, scholars have suggested a co-design collaboration with instructors and students to effectively implement formative assessment (FA) practices because it ensures a high-quality design that considers users' needs, values, and goals in a specific learning context. This study examines the effect of co-designed FA practices, in which…

We present an empirical analysis of students' use of partial derivatives in the context of problem solving in upper-division thermodynamics. Task-based individual interviews were conducted with eight middle-division physics students. The interviews involved finding a partial derivative from information presented in a table and a contour plot.…

The alternative conceptions that students hold put a brake on subsequent meaningful learning, and therefore, the identification of these wrong ideas is crucial for effective teaching and academic success. Undergraduate STEM students often perceive Chemical Thermodynamics as a difficult subject, in which entropy has been pointed out as a threshold…

A laboratory experiment that exposes students to fundamental concepts in kinetics and statistical thermodynamics to study systems of great current interest in nanotechnology by employing a foundational technique in physical chemistry is described. A modified commercial flash photolysis spectrometer was used to study photoinduced isomerization…

Seeking to foster the learning process and encourage the active participation of undergraduate students, this work proposes a new methodology that involves integrating smartphones into the learning process under a simple and accessible approach to learning in Chemistry and Physics laboratories aiming at facilitating the learning of some chemical…

This paper describes an upper-division undergraduate exercise involving the synthesis and iodometric and infrared spectroscopic analysis of the peroxide double salt [Zn(NH[subscript 3])[subscript 4]][Mo(O[subscript 2])[subscript 4]]. Here, iodometric methods are employed to determine the peroxide content of the compound, a procedure widely used…

The effects of kinetic vs thermodynamic control on "endo"/"exo" stereoisomer ratios can be observed in a simple Diels-Alder reaction between "N"-phenylmaleimide and furan. The use of microwave-promoted synthesis affords the cycloadducts in yields ranging from 65-100%, employing reaction times of 1-10 min at…

For 26 years, it has been assumed by some that the thermodynamics of open-system biochemical reactions must be executed by performing Legendre transformations on the terms involving the species whose concentrations are being held fixed. In contrast, standard nontransformed thermodynamics applies to chemical processes. However, it has recently been…

The main purpose of this study was to describe the development and use of a flowchart for preservice chemistry teachers' problem solving on the First Law of Thermodynamics. Twenty-seven undergraduate preservice chemistry teachers attending a Physical Chemistry course participated in this study. The responses of the participants to the set of test…

The Reaction Coordinate Diagram Inventory (RCDI) was developed to measure chemistry students' thinking and confidence when interpreting the kinetic and thermodynamic information encoded within reaction coordinate diagrams (RCDs). The RCDI was designed based upon analyses of qualitative data collected in semi-structured interviews with general…

This paper provides seven topics on sodium hydrogen carbonate (NaHCO[subscript 3]) and its ions for readers looking for familiar material phenomena to strengthen students' understanding of the chemical concepts of thermodynamics. The first concept is the ideal gas law, followed by the van't Hoff equation, Gibbs energy, pH change, chemical…

The need for online education continues to grow in many fields and disciplines driven by convenience and public health and safety concerns. Little is known about how online doctoral education affects the readiness of future faculty members to work and teach in university settings. This autoethnographic study explores the intentional socialization…